Explanation:
Half life of zero order and second order depends on the initial concentration. But as the given reaction slows down as the reaction proceeds, therefore, it must be second order reaction. This is because rate of reaction does not depend upon the initial concentration of the reactant.
a. As it is a second order reaction, therefore, doubling reactant concentration, will increase the rate of reaction 4 times. Therefore, the statement a is wrong.
b. Expression for second order reaction is as follows:
![\frac{1}{[A]} =\frac{1}{[A]_0} +kt](https://tex.z-dn.net/?f=%5Cfrac%7B1%7D%7B%5BA%5D%7D%20%3D%5Cfrac%7B1%7D%7B%5BA%5D_0%7D%20%2Bkt)
the above equation can be written in the form of Y = mx + C
so, the plot between 1/[A] and t is linear. So the statement b is true.
c.
Expression for half life is as follows:
![t_{1/2}=\frac{1}{k[A]_0}](https://tex.z-dn.net/?f=t_%7B1%2F2%7D%3D%5Cfrac%7B1%7D%7Bk%5BA%5D_0%7D)
As half-life is inversely proportional to initial concentration, therefore, increase in concentration will decrease the half life. Therefore statement c is wrong.
d.
Plot between A and t is exponential, therefore there is no constant slope. Therefore, the statement d is wrong
Answer:
A jump occurs when a core electron is removed.
Explanation:
A jump in ionization energy occurs when a core electron is removed. A large jump in the ionization energy easily be seen from the electronic configuration of an element.
For Beryllium, the electronic configuration of is 1s2 2s2.
There are two valence electrons in the outermost shell hence the ionization energy data for beryllium will show a sudden jump or increase in going from the second to the third ionization energy owing to the removal of a core electron
The electronic configuration for Nitrogen is 1s2 2s2 2p3. Five valence electrons are found in the outermost shell so the ionization energy data for nitrogen will show a sudden jump or increase in going from the fifth to sixth ionization energy because of the removal of a core electron
The electronic configuration of oxygen is 1s2 2s2 2p4. There are six valence electrons hence ionization energy for oxygen atom will show a sudden jump or increase in going from the sixth to the seventh ionization energy because of the removal of a core electron
The electronic configuration of Lithium is 1s2 2s1
There is one valence electron in its outermost shell so its ionization energy data will show a sudden jump or increase in going from the first to the second ionization energy because of the removal of a core electron.
Answer:
Explanation:
Primary and secondary succession occur after both human and natural events that cause drastic change in the makeup of an area. Primary succession occurs in areas where there is no soil and secondary succession occurs in areas where there is soil.
In primary succession, newly exposed or newly formed rock is colonized by living things for the first time. In secondary succession, an area previously occupied by living things is disturbed—disrupted—then recolonized following the disturbance.
Hope this helped :)
-<em>Akito</em>
Answer:
<em>At equilibrium, the rate of the forward, and the reverse reactions are equal.</em>
Explanation:
In an equilibrium chemical reaction, the rate of forward reaction, is equal to the rate of reverse reaction. Note that the reactions does not cease at equilibrium, but rather, the reactants are converted to product, at the same rate at which the product is also being converted into the reactants in the reaction. When chemical equilibrium is reached, a careful calculation of the value of equilibrium constant is approximately equal to 1.
NB: If the value of equilibrium constant is far far greater than 1, then the reaction will favors more of the forward reaction, and if far far less than 1, the reaction will favor more of the reverse reaction.
