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lubasha [3.4K]
3 years ago
10

A student decreases the temperature of 556 cm^3 balloon from 278 K to 231 K. Assuming constant pressure, what should the new vol

ume of the balloon be?
Chemistry
1 answer:
julia-pushkina [17]3 years ago
6 0
In this problem, Charles' law is applicable since constant pressure with varying volume and temperature are given. Charles' law derived from ideal gas law is expressed as \frac{ V_{1} }{ T_{1} }=  \frac{ V_{2} }{ T_{2} }. Subsituting V1=556 cm3, T1=278 K and T2=231 K, V2 or the new volume is 462 cm3. 
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Using a 300 MHz NMR instrument:
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Explanation:

The Downfield Shift (Hz) is given by the formula

Downfield Shift (Hz) = Chemical Shift (ppm) x Spectrometer Frequency (Hz)

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a. fspec = 300 MHz, Chem. Shift = 2.5ppm, 1MHz = 10⁶ Hz, 1ppm (parts per million) = 10⁻⁶

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The signal comes at 4.0 ppm

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Downfield Shift (Hz) = 2(ppm) x 300 (MHz) x (1Hz/10⁶MHz) x (10⁻⁶/1ppm) = 600 Hz

The two peaks are separated by 600Hz

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