Answers and Explanation:
a)- The chemical equation for the corresponden equilibrium of Ka1 is:
2. HNO2(aq)⇌H+(aq)+NO−2
Because Ka1 correspond to a dissociation equilibrium. Nitrous acid (HNO₂) losses a proton (H⁺) and gives the monovalent anion NO₂⁻.
b)- The relation between Ka and the free energy change (ΔG) is given by the following equation:
ΔG= ΔGº + RT ln Q
Where T is the temperature (T= 25ºc= 298 K) and R is the gases constant (8.314 J/K.mol)
At the equilibrium: ΔG=0 and Q= Ka. So, we can calculate ΔGº by introducing the value of Ka:
⇒ 0 = ΔGº + RT ln Ka
ΔGº= - RT ln Ka
ΔGº= -8.314 J/K.mol x 298 K x ln (4.5 10⁻⁴)
ΔGº= 19092.8 J/mol
c)- According to the previous demonstation, at equilibrium ΔG= 0.
d)- In a non-equilibrium condition, we have Q which is calculated with the concentrations of products and reactions in a non equilibrium state:
ΔG= ΔGº + RT ln Q
Q= ((H⁺) (NO₂⁻))/(HNO₂)
Q= ( (5.9 10⁻² M) x (6.7 10⁻⁴ M) ) / (0.21 M)
Q= 1.88 10⁻⁴
We know that ΔGº= 19092.8 J/mol, so:
ΔG= ΔGº + RT ln Q
ΔG= 19092.8 J/mol + (8.314 J/K.mol x 298 K x ln (1.88 10⁻⁴)
ΔG= -2162.4 J/mol
Notice that ΔG<0, so the process is spontaneous in that direction.
Answer:
Binary molecular compounds are the compounds consisting of two non-metallic elements. Examples of binary molecular compounds include: NO2, HCl, HF, P2O5 e.t.c.
Rules For Naming Binary Molecular Compounds
Naming binary molecular compounds is quite easy,
1. The first element is given its name.
2. The second element is given its root name (such as, hydro, carb,ox, chlor e.t.c.) followed by suffix <em>ide.</em>
Name of N2O4 - Dinitrogen tetraoxide
Chemical Formula of;
iodic acid: HI
disulfur trioxide: S2O3
dinitrogen monoxide: N2O
hydrofluoric acid: HF
Difference between Binary acid and an oxyacid
An oxyacid is an acid consisting of an oxygen atom bonded to a hydrogen atom and at least one other non-metallic element. Examples of oxyacids include HNO3, H2SO4 e.t.c.
Binary acids are the acids consisting of hydrogen atom bonded to a non-metallic element. Examples include HF, HCl, HI e.t.c.
Nuclear power plant because that is a fission reaction and fusion would melt the power plant
Answer : The volume of stock solution needed are, 12.5 mL
Explanation :
Formula used :
where,
are the initial molarity and volume of copper (II) chloride.
are the final molarity and volume of stock solution of copper (II) chloride.
We are given:
Putting values in above equation, we get:
Hence, the volume of stock solution needed are, 12.5 mL
I think the correct answer from the choices listed above is the last option. The pressure of an enclosed gas depends on the number of molecules in a unit volume and their average kinetic energy, its chemical composition, the altitude about sea level and the number of atoms per molecule. Hope this helps. Have a nice day.
