Suppose we have 100 gr of the substance. Then by weight, it would contain 44.77 gr of C, 7.46 gr of H and 47.76 gr of S. We need to look up the atomic weights of these atoms; M_H=1, M_C=12, M_S=32. The following formula holds (where n are the moles of the substance, M its molecular mass and m its mass): n=m/M. Substituting the known quantities for each element, we get that the substance has 3.73 moles of C, 7.46 moles of H and 1.49 moles of S. In the empirical formula for the molecule, all atoms appear an integer amout of times. Hence, for every mole of Sulfur, we have 2.5 moles of C and 5 moles of H (by taking the moles ratios). Thus, for every 2 moles of sulfur, we have 5 moles of C and 10 moles of H. Now that all the coefficients are integer, we have arrived at an empirical formula for the skunk spray agent:
Given buffer:
potassium hydrogen tartrate/dipotassium tartrate (KHC4H4O6/K2C4H4O6 )
[KHC4H4O6] = 0.0451 M
[K2C4H4O6] = 0.028 M
Ka1 = 9.2 *10^-4
Ka2 = 4.31*10^-5
Based on Henderson-Hasselbalch equation;
pH = pKa + log [conjugate base]/[acid]
where pka = -logKa
In this case we will use the ka corresponding to the deprotonation of the second proton i.e. ka2
pH = -log Ka2 + log [K2C4H4O6]/[KHC4H4O6]
= -log (4.31*10^-5) + log [0.0451]/[0.028]
pH = 4.15
I’m sorry no one helped you with those questions. But could you please be a doll and give me the answer for the multiple-choice questions 1-15. Pleaseee I’m so desperate.?
Answer:
We need 92.3 grams of sodium azide
Explanation:
Step 1: Data given
Mass of nitrogen gas = 59.6 grams
Molar mass of nitrogen gas = 28.0 g/mol
Molar mass of sodium azide = 65.0 g/mol
Step 2: The balanced equation
2NaN3 → 2Na + 3N2
Step 3: Calculate moles nitrogen gas
Moles N2 = mass N2 / molar mass N2
Moles N2 = 59.6 grams/ 28.0 g/mol
Moles N2 = 2.13 moles
Step 4: Calculate moles NaN3
for 2 moles NaN3 we'll have 2 moles Na and 3 moles N2
For 2.13 moles N2 we need 2/3* 2.13 = 1.42 moles NaN3
Step 5: Calculate mass NaN3
Mass NaN3 = Moles NaN3 * molar mass NaN3
Mass NaN3 = 1.42 moles * 65.0 g/mol
Mass NaN3 = 92.3 grams
We need 92.3 grams of sodium azide
Answer:
(a) 
(b) 
(c) 
(d) 
(e) 
Explanation:
To calculate de pH of an acid solution the formula is:
![pH = -Log ([H^{+}]) = 1](https://tex.z-dn.net/?f=pH%20%3D%20-Log%20%28%5BH%5E%7B%2B%7D%5D%29%20%3D%201)
were [H^{+}] is the concentration of protons of the solution. Therefore it is necessary to know the concentration of the protons for every solution in order to solve the problem.
(a) and (c) are strong acids so they dissociate completely in aqueous solution. Thus, the concentration of the acid is the same as the protons.
(b) and (e) are strong bases so they dissociate completely in aqueous solution too. Thus, the concentration of the base is the same as the oxydriles. But in this case it is necessary to consider the water autoionization to calculate the protons concentration:
![K_{w} =[H^{+} ][OH^{-}]=10^{-14}](https://tex.z-dn.net/?f=K_%7Bw%7D%20%3D%5BH%5E%7B%2B%7D%20%5D%5BOH%5E%7B-%7D%5D%3D10%5E%7B-14%7D)
clearing the ![[H^{+} ]](https://tex.z-dn.net/?f=%5BH%5E%7B%2B%7D%20%5D)
![[H^{+} ]=\frac{10^{-14}}{[OH^{-}]}](https://tex.z-dn.net/?f=%5BH%5E%7B%2B%7D%20%5D%3D%5Cfrac%7B10%5E%7B-14%7D%7D%7B%5BOH%5E%7B-%7D%5D%7D)
(d) is a weak base so it is necessary to solve the equilibrium first, knowing 
The reaction is
→
so the equilibrium is

clearing the <em>x</em>

![x=[H^{+}]=4.93x10^{-10}](https://tex.z-dn.net/?f=x%3D%5BH%5E%7B%2B%7D%5D%3D4.93x10%5E%7B-10%7D)