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Alecsey [184]
4 years ago
10

The Wolff-Kishner reaction involves the reaction of an aldehyde/ketone with hydrazine in the presence of KOH. The process is use

ful for converting an aldehyde or ketone into an alkane. The reaction involves formation of a hydrazone, followed by base-catalyzed double-bond migration, loss of N2 gas to give a carbanion, and protonation to give the alkane. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions

Chemistry
1 answer:
Ivan4 years ago
6 0

Answer:

in the attached image is the reaction mechanism.

Explanation:

The first reaction (reaction 1) shown in the attached image is the Wolff-Kishner reduction, which is characterized when the carbonyl is reduced to an alkane in the presence of a hydrazine and a base. In reaction 1, the aldehyde reacts with hydrazine to produce oxime. This mechanism begins with the attack of the amine on the carbonyl group. Proton exchange happens and the water leaves the molecule.

In reaction 2, the KOH is deprotoned in nitrogen and organized to form the bond between the nitrogen molecule. this deprotonation releases the nitrogen gas

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Please help me name this alkane
Mrac [35]
I assume you are already familiar with the IUPAC rules.  I will be referring to the rule number where applicable.  If you do not have a copy of the IUPAC rules, please let me know by a comment or PM.

Alkane (A)
The first one is tricky, because the longest straight chain is not as drawn, but along a "branch".  See first image.
Since there are 10 carbon atoms in the longest chain, the parent chain will be named decane.
The first substituent occurs in C3, that explains why the parent chain is named from right to left.
Now the substituents:
C3 :  Cl and CH3, so 3-chloro  3-methyl
C6 :  The Y-shape is named isopropyl, so 6-isopropyl
C7 :  Substituent is a straight chain with 2 carbon atoms, so 7-ethyl
The complete name is therefore
3-chloro-7-ethyl-3-methyl-6-isopropyl-decane
Note that order is according to alphabetic order of the substituent name without the prefixes (explains why isopropyl comes after methyl)

Alkane (B)
Again, first step is to look for the longest chain, which is 11 (undecane), as numbered in image 2.
Numbering starts from the 2,2-dichloro end because it gives the lowest number for the locant.
C2 2,2-dichloro  (2 branches, each is Cl)
C4 4-methyl  (1 carbon atom)C5 5-ethyl   (2 carbon atoms)
C8 8-ethyl    
C9 9-methyl
So the complete name is 
2-2-dichloro-5,8-diethyl-4,9-dimethyl-undecane

Alkane (C)
Here there are 9 carbon atoms (nonane) in the longest chain.
The locants of substituents are identical from either end.  Here I choose the one with the smaller number of the first substitutent 2-methyl instead of 2,2-dimethyl, resulting the numbering starting from the right.  I hope I am right here.
C2 1-methyl
C3 1-methyl
C4 1-methyl
C5 1-methyl
C6 6-fluro-6-iodo
C7 1-methyl
C8 8,8-dimethyl
So the complete name becomes
6-fluoro-6-iodo-2,3,4,5,7,8,8-heptamethyl nonane

To @study77 and anyone reading this answer:
Please check and understand everything I did in case I slipped somewhere.  Any suggestion for improvement or corrections will be most appreciated.

8 0
3 years ago
Consider the KF molecule, which has an ionic bond. The bond length is 2.17 x 1010 m (a) Calculate the energy required to dissoci
Natasha2012 [34]

Answer:

a) +640 kJ/mol or +1.06x10⁻¹⁸ J

b) +276 kJ/mol

Explanation:

To dissociate the molecule, the bond must be broken, thus, it's necessary energy equal to the energy of the bond, which can be calculated by:

E = (Q1*Q2)/(4*π*ε*r)

Where Q is the charge of the ions, ε is a constant (8.854x10⁻¹²C²J ⁻¹ m⁻¹), and r is the bond length. Each one of the ions has a charge equal to 1. The elementary charge is 1.602x10⁻¹⁹C, which will be the charge of them.

1 mol has 6.022x10²³ molecules (Avogadros' number), so the energy of 1 mol is the energy of 1 molecule multiplied by it:

E = 6.022x10²³ *(1.602x10⁻¹⁹)²/(4π*8.854x10⁻¹²*2.17x10⁻¹⁰)

E = +640113 J/mol

E = +640 kJ/mol

Or at 1 molecule: E =640/6.022x10²³ = +1.06x10⁻²¹ kJ = +1.06x10⁻¹⁸ J

b) The energy variation to dissociate the molecule at its neutral atoms is the energy of dissociation less the difference of the ionization energy of K and the electron affinity of F (EA):

498 = 640 - (418 - EA)

640 -418 + EA = 498

222 + EA = 498

EA = +276 kJ/mol

8 0
4 years ago
How is heating of sugar and heating of ammonium chloride different from each other? Explain your answer.
algol13
When sugar is heated it melts and then caramelize giving of water. After this, it turns blank (carbon) and then coverts to co2 (carbon dioxide) .
So, heating of sugar is an endothermic , decomposition and oxidation reaction.
  When Ammonium Chloride is heated , it directly goes from solid state to vapour state without changing into liquid state.
So, heating of Ammonium Chloride is an example of sublimation reaction.
3 0
4 years ago
The electronic configuration of an element is 1s^2 2s^2 2p^6. Hkw many valence electrons does it have
Aliun [14]
It has 8 valence electrons.
5 0
4 years ago
How Many Moles Of HCl Need To Be Added To 150.0 ML Of 0.50 M NaZ To Have A Solution With A PH Of 6.50
Aleks04 [339]

The number of mole of HCl needed for the solution is 1.035×10¯³ mole

<h3>How to determine the pKa</h3>

We'll begin by calculating the pKa of the solution. This can be obtained as follow:

  • Equilibrium constant (Ka) = 2.3×10¯⁵
  • pKa =?

pKa = –Log Ka

pKa = –Log 2.3×10¯⁵

pKa = 4.64

<h3>How to determine the molarity of HCl </h3>
  • pKa = 4.64
  • pH = 6.5
  • Molarity of salt [NaZ] = 0.5 M
  • Molarity of HCl [HCl] =?

pH = pKa + Log[salt]/[acid]

6.5 = 4.64 + Log[0.5]/[HCl]

Collect like terms

6.5 – 4.64 = Log[0.5]/[HCl]

1.86 = Log[0.5]/[HCl]

Take the anti-log

0.5 / [HCl] = anti-log 1.86

0.5 / [HCl] = 72.44

Cross multiply

0.5 = [HCl] × 72.44

Divide both side by 72.44

[HCl] = 0.5 / 72.4

[HCl] = 0.0069 M

<h3>How to determine the mole of HCl </h3>
  • Molarity of HCl = 0.0069 M
  • Volume = 150 mL = 150 / 1000 = 0.15 L
  • Mole of HCl =?

Mole = Molarity x Volume

Mole of HCl = 0.0069 × 0.15

Mole of HCl = 1.035×10¯³ mole

<h3>Complete question</h3>

How many moles of HCl need to be added to 150.0 mL of 0.50 M NaZ to have a solution with a pH of 6.50? (Ka of HZ is 2.3 x 10 -5 .) Assume negligible volume of the HCl

Learn more about pH of buffer:

brainly.com/question/21881762

7 0
3 years ago
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