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max2010maxim [7]
3 years ago
9

Calculate the volume occupiedat s.t.p by 6.89gas [H = 10, N = 14​

Chemistry
1 answer:
Nadya [2.5K]3 years ago
8 0

Answer:

9.07 L

Explanation:

<em>Calculate the volume occupied at s.t.p by 6.89 g of NH₃ gas [H = 1.0, N = 14.0​].</em>

Step 1: Given and required data

  • Mass of NH₃ (m): 6.89 g
  • Molar mass of NH₃ (M): 17.0 g/mol

Step 2: Calculate the moles (n) of NH₃

We will use the following epxression.

n = m / M

n = 6.89 g / (17.0 g/mol) = 0.405 mol

Step 3: Calculate the volume occupied by 0.405 moles of NH₃ at STP

At STP, 1 mole of NH₃ occupies 22.4 L (assuming ideal behavior).

0.405 mol × 22.4 L/1 mol = 9.07 L

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An equilibrium mixture of PCl5(g), PCl3(g), and Cl2(g) has partial pressures of 217.0 Torr, 13.2 Torr, and 13.2 Torr, respective
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Answer:

The new partial pressures after equilibrium is reestablished:

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Explanation:

PCl_3(g) + Cl_2(g)\rightleftharpoons PCl_5(g)

At equilibrium before adding chlorine gas:

Partial pressure of the PCl_3=p_1=13.2 Torr

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Partial pressure of the PCl_5=p_3=217.0 Torr

The expression of an equilibrium constant is given by :

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At equilibrium after adding chlorine gas:

Partial pressure of the PCl_3=p_1'=13.2 Torr

Partial pressure of the Cl_2=p_2'=?

Partial pressure of the PCl_5=p_3'=217.0 Torr

Total pressure of the system = P = 263.0 Torr

P=p_1'+p_2'+p_3'

263.0Torr=13.2 Torr+p_2'+217.0 Torr

p_2'=32.8 Torr

PCl_3(g) + Cl_2(g)\rightleftharpoons PCl_5(g)

At initail

(13.2) Torr     (32.8) Torr                        (13.2) Torr

At equilbriumm

(13.2-x) Torr     (32.8-x) Torr                        (217.0+x) Torr

K_p=\frac{p_3'}{p_1'\times p_2'}

1.245=\frac{(217.0+x)}{(13.2-x)(32.8-x)}

Solving for x;

x = 6.402 Torr

The new partial pressures after equilibrium is reestablished:

p_1'=(13.2-x) Torr=(13.2-6.402) Torr=6.798 Torr

p_2'=(32.8-x) Torr=(32.8-6.402) Torr=26.398 Torr

p_3'=(217.0+x) Torr=(217+6.402) Torr=223.402 Torr

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