Nitrogen (N2) and hydrogen (H2) gases react to form ammonia, which requires -99.4 J/K of standard entropy (ΔS°).
What is standard entropy?
The difference between the total standard entropies of the reaction mixture and the summation of the standard entropies of the outputs is the standard entropy change. Each entropy in the balanced equation needs to be compounded by its coefficient, as shown by the letter "n."
Calculation:
Balancing the given reaction following-
1/2 N₂(g) + 3/2 H₂ (g)→ NH₃ (g)
ΔS° = [1 mol x S° (NH₃)g] - [1/2 mol x S° (N₂)g] - [3/2 mol x S°(H₂)g]
Here S° = standard entropy of the system
Insert into the aforementioned equation all the typical entropy values found in the literature:
ΔS° = [1 mol x 192.45 J/mol.K] - [1/2 mol x 191.61 J/mol.K] - [3/2 mol x 130.684 J/mol.K]
⇒ΔS° = - 99.4 J/K
Therefore, the standard entropy, ΔS° is -99.4 J/K.
Learn more about standard entropy here:
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The balanced equation between NaOH and H₂SO₄ is as follows
2NaOH + H₂SO₄ ---> Na₂SO₄ + 2H₂O
stoichiometry of NaOH to H₂SO₄ is 2:1
number of moles of NaOH moles reacted = molarity of NaOH x volume
number of NaOH moles = 0.08964 mol/L x 27.86 x 10⁻³ L = 2.497 x 10⁻³ mol
according to molar ratio of 2:1
2 mol of NaOH reacts with 1 mol of H₂SO₄
therefore 2.497 x 10⁻³ mol of NaOH reacts with - 1/2 x 2.497 x 10⁻³ mol of H₂SO₄
number of moles of H₂SO₄ reacted - 1.249 x 10⁻³ mol
Number of H₂SO₄ moles in 34.53 mL - 1.249 x 10⁻³ mol
number of H₂SO₄ moles in 1000 mL - 1.249 x 10⁻³ mol / 34.53 x 10⁻³ L = 0.03617 mol
molarity of H₂SO₄ is 0.03617 M
Density gives mass of object per volume...... Here, density is given 8.90 g/cm3 therefore, per cubic centimeter contains 8.90 g Ni. mole of Ni = mass / atomic mass = 8.90 / 58.6934 = 0.1516 mole number of atoms: mole * 6.022 * 10^23 = 0.1516 * 6.022 * 10^23 = 0.9129 * 10^23 = 0.9 * 10^23 (approx.)
