Answer:
12 atm
Explanation:
First, let us convert Celcius into Kelvin: 28.0 °C = 301.15 K and 129.0 °C = 402.15 K
For this question we must employ the Combined Gas Law: 
, where 
is the initial pressure and 
is the new pressure.
We know that intitially, P=9 atm, V=30 L, and T=301.15K. From our problem, only temperature and pressure changes, while the number of moles, volume and the gas constant, R, stay the same, so they are irrelevant.
Thus, the filled out Combined Gas Law would be:
=
, where the volume, moles of gas, and R are cancelled out.
We can manipulate this equation to derive the new pressure. We find that
9atm≈0.74885.
This means that
≈9/0.74885≈12 atm
Answer:
The pH of the buffer solution = 8.05
Explanation:
Using the Henderson - Hasselbalch equation;
pH = pKa₂ + log ( [HPO₄²-]/[H₂PO4⁻]
where pKa₂ = -log (Ka₂) = -log ( 6.1 * 10⁻⁸) = 7.21
Concentration of OH⁻ added = 0.069 M (i.e. 0.069 mol/L)
[H₂PO4⁻] after addition of OH⁻ = 0.165 - 0.069 = 0.096 M
[HPO₄²-] after addition of OH⁻ = 0.594 + 0.069 = 0.663 M
Therefore,
pH = 7.21 + log (0.663 / 0.096)
pH = 7.21 + 0.84
pH = 8.05
Heat capacity of aluminium = 0.900 J/g°C
While heat capacity of water = 4.186 J/g°C
Heat = heat gained by water + heat gained by aluminium
Heat gained by water = 100 × 4.186 × 30.5
= 12767.3 Joules
Heat gained by aluminium = 15 × 0.9 × 30.5
= 411.75 Joules
Heat required = 13179.05 Joules or 13.179 kJoules
