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bixtya [17]
3 years ago
14

For a given reaction, ΔS = +106 J/mol ⋅ K, and the reaction is spontaneous at temperatures above the crossover temperature, 446

K. The value of ΔH = _______ kJ/mol, assuming that ΔH and ΔS do not vary with temperature.
Chemistry
1 answer:
solniwko [45]3 years ago
7 0

Answer:  47.276 kJ/mol

Explanation:

According to Gibb's equation:

\Delta G=\Delta H-T\Delta S

\Delta G = Gibbs free energy  

\Delta H = enthalpy change

\Delta S = entropy change  = +106 J/mol

T = temperature in Kelvin  = 446 K

\Delta G= +ve, reaction is non spontaneous

\Delta G= -ve, reaction is spontaneous

\Delta G= 0, reaction is in equilibrium

\Delta H=T\Delta S

\Delta H=T\Delta S

\Delta H=446K\times +106J/Kmol=47276J/mol=47.276kJ/mol   (1kJ=1000J)

Thus the value of ΔH = 47.276 kJ/mol, assuming that ΔH and ΔS do not vary with temperature.

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The temperature that must be to freeze the solution would be -21.1 ° C.

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To calculate the freezing temperature we must take into account the following information.

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According to the above, it can be inferred that the puddle has a 50% concentration of salt because they had 12 kg of water and 6 kg of salt.

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