A rigid tank of air is cooled (temperature decreased). The volume has to remain constant because it is a rigid tank. The air pre
2 answers:
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Answer:
(a) ΔU=747J
(b) γ=1.3
Explanation:
For (a) change in internal energy
According to first law of thermodynamics the change in internal energy is given as
ΔU=Q-W
Substitute the given values
ΔU=970J-223J
ΔU=747J
For(b) γ for the gas.
We can calculate γ by ratio of heat capacities of the gas
γ=Cp/Cv
Where Cp is the molar heat capacity at constant pressure
Cv is the molar heat capacity at constant volume
To calculate γ we first need to find Cp and Cv
So
For Cp
As we know
Q=nCpΔT
Cp=(Q/nΔT)
From relation of Cv and Cp we know that
Cp=Cv+R
Where R is gas constant equals to 8.314J/mol.K
So
So
γ=Cp/Cv
γ=[(37J/mol.K) / (28.687J/mol.K)]
γ=1.3
Answer:
Explanation:
The equilibrium mechanism for the reversible acid is catalyzed by the isomerization of non conjugated β, γ- unsaturated ketones, like 3-cyclohexanone to their conjugated α, I²- unsaturated isomers.
Oxygen of the Carbonyl group in the ketone is protonated by the acid and this is followed by the abstraction of an α- hydrogen from the protonated 3-cyclo hexanone to yield ethanol
2-cyclo hexanone can be obtained by acid catalyzation of 3-cyclohexanone isomers through the formation of it's "enol".
