Jackson, the epitome of the frontiersman, resented the bank's lack of funding for expansion into the unsettled Western territories. Jackson also objected to the bank's unusual political and economic power and to the lack of congressional oversight over its business dealings.
A molecule with two strong bond dipoles can have no molecular dipole if the bond dipoles cancel each other out by pointing in exactly opposite directions. For example, in carbon dioxide (a linear molecule), the carbon-oxygen bonds have a <span>large dipole moment. However, because one dipole points to the left and the other to the right the dipole is cancelled.</span>
In a combustion of a hydrocarbon compound, 2 reactions are happening per element:
C + O₂ → CO₂
2 H + 1/2 O₂ → H₂O
Thus, we can determine the amount of C and H from the masses of CO₂ and H₂O produced, respectively.
1.) Compute for the amount of C in the compound. The data you need to know are the following:
Molar mass of C = 12 g/mol
Molar mass of CO₂ = 44 g/mol
Solution:
0.5008 g CO₂*(1 mol CO₂/ 44 g)*(1 mol C/1 mol CO₂) = 0.01138 mol C
0.01138 mol C*(12 g/mol) = 0.13658 g C
Compute for the amount of H in the compound. The data you need to know are the following:
Molar mass of H = 1 g/mol
Molar mass of H₂O = 18 g/mol
Solution:
0.1282 g H₂O*(1 mol H₂O/ 18 g)*(2 mol H/1 mol H₂O) = 0.014244 mol H
0.014244 mol H*(1 g/mol) = 0.014244 g H
The percent composition of pure hydrocarbon would be:
Percent composition = (Mass of C + Mass of H)/(Mass of sample) * 100
Percent composition = (0.13658 g + 0.014244 g)/(<span>0.1510 g) * 100
</span>Percent composition = 99.88%
2. The empirical formula is determined by finding the ratio of the elements. From #1, the amounts of moles is:
Amount of C = 0.01138 mol
Amount of H = 0.014244 mol
Divide the least number between the two to each of their individual amounts:
C = 0.01138/0.01138 = 1
H = 0.014244/0.01138 = 1.25
The ratio should be a whole number. So, you multiple 4 to each of the ratios:
C = 1*4 = 4
H = 1.25*4 = 5
Thus, the empirical formula of the hydrocarbon is C₄H₅.
3. The molar mass of the empirical formula is
Molar mass = 4(12 g/mol) + 5(1 g/mol) = 53 g/mol
Divide this from the given molecular weight of 106 g/mol
106 g/mol / 53 g/mol = 2
Thus, you need to multiply 2 to the subscripts of the empirical formula.
Molecular Formula = C₈H₁₀
II. sulfur (S) and carbon (C)
and
III. fluorine (F) and oxygen (O)
will form covalent bonds, so the answer will be:
e. II and III
Explanation:
To know is what type of bond is formed between atoms we need to look at the electronegativity difference between the atoms.
If the electronegativity difference is less than 0.4 there is a nonpolar covalent bond.
If the electronegativity difference is between 0.4 and 1.8 there is a polar covalent bond. (if is a metal involved we consider the bond to be ionic)
If the electronegativity difference is greater then 1.8 there is an ionic bond.
We have the following cases:
I. lithium (Li) and sulfur (S)
electronegativity difference = 2.5 (S) - 1 (Li) = 1.5 but because there is a metal involved the bond will be ionic
II. sulfur (S) and carbon (C)
electronegativity difference = 2.5 (S) - 2.5 (C) = 0 so the bond will be nonpolar covalent
III. fluorine (F) and oxygen (O)
electronegativity difference = 4 (F) - 3.5 (O) = 0.5 so the bond will be polar covalent bond.
Learn more about:
covalent and ionic bonds
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The answer is-
is octahedral in electronic and molecular geometry with 6 Fluorine atoms bonded to central atom S.
Lewis structures are the diagrams in which the valence electrons of the atoms of a compound are arranged around the atoms showing the bonding between the atom and the lone pair of electrons existing in the molecule.
Determine the molecular geometry of
.
- Valence Shell Electron Pair Repulsion theory is commonly known as VSEPR theory and it helps to predict the geometry of molecules.
- According to this theory, electrons are arranged around the central atom of the molecule in such a way that there is minimum electrostatic repulsion between these electrons.
- Now, calculate the total number of valence electrons in
.

Valence electrons of S = 6
Valence electrons of F = 7
Thus, the valence electrons in
are-

- The Lewis structure of
is - (Image attached). - In the structure, the number of atoms bonded to central atom (S) = 6.
- Number of non-bonding electron pairs on the central atom = 0 (as all the valence electrons are bonded to F).
- Electronic geometry in case of 6 bond pairs is octahedral.
- Molecular geometry us also octahedral with bond angles 90°.
- Central atom is sp3d2 hybridised.
is a non-polar molecule.
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