Answer:
a)W=12.62 kJ/mol
b)W=12.59 kJ/mol
Explanation:
At T = 100 °C the second and third virial coefficients are
B = -242.5 cm^3 mol^-1
C = 25200 cm^6 mo1^-2
Now according isothermal work of one mole methyl gas is
W=-
a=
b=
from virial equation
And
a=
b=
Now calculate V1 and V2 at given condition
Substitute given values = 1 x 10^5 , T = 373.15 and given values of coefficients we get
Solve for V1 by iterative or alternative cubic equation solver we get
Similarly solve for state 2 at P2 = 50 bar we get
Now
a=241.33
b=30780
After performing integration we get work done on the system is
W=12.62 kJ/mol
(b) for Z = 1 + B' P +C' P^2 = PV/RT by performing differential we get
dV=RT(-1/p^2+0+C')dP
Hence work done on the system is
a=
b=
by substituting given limit and P = 1 bar , P2 = 50 bar and T = 373 K we get work
W=12.59 kJ/mol
The work by differ between a and b because the conversion of constant of virial coefficients are valid only for infinite series
Answer:
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Explanation:
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Answer:
a) at T = 5800 k
band emission = 0.2261
at T = 2900 k
band emission = 0.0442
b) daylight (d) = 0.50 μm
Incandescent ( i ) = 1 μm
Explanation:
To Calculate the band emission fractions we will apply the Wien's displacement Law
The ban emission fraction in spectral range λ1 to λ2 at a blackbody temperature T can be expressed as
F ( λ1 - λ2, T ) = F( 0 ----> λ2,T) - F( 0 ----> λ1,T )
<em>Values are gotten from the table named: blackbody radiati</em>on functions
<u>a) Calculate the band emission fractions for the visible region</u>
at T = 5800 k
band emission = 0.2261
at T = 2900 k
band emission = 0.0442
attached below is a detailed solution to the problem
<u>b)calculate wavelength corresponding to the maximum spectral intensity</u>
For daylight ( d ) = 2898 μm *k / 5800 k = 0.50 μm
For Incandescent ( i ) = 2898 μm *k / 2900 k = 1 μm
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Explanation: