The molar extinction coefficient is 15,200
.
The formula to be used to calculate molar extinction coefficient is -
A = ξcl, where A represents absorption, ξ refers molar extinction coefficient, c refers to concentration and l represents length.
The given values are in required units, hence, there is no need to convert them. Directly keeping the values in formula to find the value of molar extinction coefficient.
Rewriting the formula as per molar extinction coefficient -
ξ = 
ξ = 
Performing multiplication in denominator to find the value of molar extinction coefficient
ξ =
Performing division to find the value of molar extinction coefficient
ξ = 15,200 
Hence, the molar extinction coefficient is 15,200
.
Learn more about molar extinction coefficient -
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Explanation:
<em><u>2Al + 2NaOH + 6H2O → 2Na[Al(OH)4] + 3H2</u></em>
<em><u>
</u></em>
<u>Answer:</u> The value of
of the reaction is 28.38 kJ/mol
<u>Explanation:</u>
For the given chemical reaction:

- The equation used to calculate enthalpy change is of a reaction is:
![\Delta H^o_{rxn}=\sum [n\times \Delta H^o_f_{(product)}]-\sum [n\times \Delta H^o_f_{(reactant)}]](https://tex.z-dn.net/?f=%5CDelta%20H%5Eo_%7Brxn%7D%3D%5Csum%20%5Bn%5Ctimes%20%5CDelta%20H%5Eo_f_%7B%28product%29%7D%5D-%5Csum%20%5Bn%5Ctimes%20%5CDelta%20H%5Eo_f_%7B%28reactant%29%7D%5D)
The equation for the enthalpy change of the above reaction is:
![\Delta H^o_{rxn}=[(1\times \Delta H^o_f_{(SO_2Cl_2(g))})]-[(1\times \Delta H^o_f_{(SO_2(g))})+(1\times \Delta H^o_f_{(Cl_2(g))})]](https://tex.z-dn.net/?f=%5CDelta%20H%5Eo_%7Brxn%7D%3D%5B%281%5Ctimes%20%5CDelta%20H%5Eo_f_%7B%28SO_2Cl_2%28g%29%29%7D%29%5D-%5B%281%5Ctimes%20%5CDelta%20H%5Eo_f_%7B%28SO_2%28g%29%29%7D%29%2B%281%5Ctimes%20%5CDelta%20H%5Eo_f_%7B%28Cl_2%28g%29%29%7D%29%5D)
We are given:

Putting values in above equation, we get:
![\Delta H^o_{rxn}=[(1\times (-364))]-[(1\times (-296.8))+(1\times 0)]=-67.2kJ/mol=-67200J/mol](https://tex.z-dn.net/?f=%5CDelta%20H%5Eo_%7Brxn%7D%3D%5B%281%5Ctimes%20%28-364%29%29%5D-%5B%281%5Ctimes%20%28-296.8%29%29%2B%281%5Ctimes%200%29%5D%3D-67.2kJ%2Fmol%3D-67200J%2Fmol)
- The equation used to calculate entropy change is of a reaction is:
![\Delta S^o_{rxn}=\sum [n\times \Delta S^o_f_{(product)}]-\sum [n\times \Delta S^o_f_{(reactant)}]](https://tex.z-dn.net/?f=%5CDelta%20S%5Eo_%7Brxn%7D%3D%5Csum%20%5Bn%5Ctimes%20%5CDelta%20S%5Eo_f_%7B%28product%29%7D%5D-%5Csum%20%5Bn%5Ctimes%20%5CDelta%20S%5Eo_f_%7B%28reactant%29%7D%5D)
The equation for the entropy change of the above reaction is:
![\Delta S^o_{rxn}=[(1\times \Delta S^o_{(SO_2Cl_2(g))})]-[(1\times \Delta S^o_{(SO_2(g))})+(1\times \Delta S^o_{(Cl_2(g))})]](https://tex.z-dn.net/?f=%5CDelta%20S%5Eo_%7Brxn%7D%3D%5B%281%5Ctimes%20%5CDelta%20S%5Eo_%7B%28SO_2Cl_2%28g%29%29%7D%29%5D-%5B%281%5Ctimes%20%5CDelta%20S%5Eo_%7B%28SO_2%28g%29%29%7D%29%2B%281%5Ctimes%20%5CDelta%20S%5Eo_%7B%28Cl_2%28g%29%29%7D%29%5D)
We are given:

Putting values in above equation, we get:
![\Delta S^o_{rxn}=[(1\times 311.9)]-[(1\times 248.2)+(1\times 223.0)]=-159.3J/Kmol](https://tex.z-dn.net/?f=%5CDelta%20S%5Eo_%7Brxn%7D%3D%5B%281%5Ctimes%20311.9%29%5D-%5B%281%5Ctimes%20248.2%29%2B%281%5Ctimes%20223.0%29%5D%3D-159.3J%2FKmol)
To calculate the standard Gibbs's free energy of the reaction, we use the equation:

where,
= standard enthalpy change of the reaction =-67200 J/mol
= standard entropy change of the reaction =-159.3 J/Kmol
Temperature of the reaction = 600 K
Putting values in above equation, we get:

Hence, the value of
of the reaction is 28.38 kJ/mol
44. (a) N2O3 (b) SF4 (c) AlCl3 (d) Li2CO3
46. H Br
δ+ δ−
48. The metallic potassium atoms lose one electron and form +1 cations,
and the nonmetallic fluorine atoms gain one electron and form –1 anions.
K → K+
+ e–
19p/19e–
19p/18e–
F + e–
→ F–
9p/9e–
9p/10e–
The ionic bonds are the attractions between K+
cations and F–
anions.
50. See Figure 3.6.
52. (a) covalent…nonmetal-nonmetal (b) ionic…metal-nonmetal
54. (a) all nonmetallic atoms - molecular (b) metal-nonmetal - ionic
56. (a) 7 (b) 4
58. Each of the following answers is based on the assumption that nonmetallic
atoms tend to form covalent bonds in order to get an octet (8) of
electrons around each atom, like the very stable noble gases (other than
helium). Covalent bonds (represented by lines in Lewis structures) and lone
pairs each contribute two electrons to the octet.
(a) oxygen, O
If oxygen atoms form two covalent bonds, they will have an octet of electrons
around them. Water is an example:
H O H
(b) fluorine, F
If fluorine atoms form one covalent bond, they will have an octet of electrons
around them. Hydrogen fluoride, HF, is an example:
H F
(c) carbon, C
If carbon atoms form four covalent bonds, they will have an octet of electrons
around them. Methane, CH4, is an example:
H H
H
H
C
(d) phosphorus, P
If phosphorus atoms form three covalent bonds, they will have an octet