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Over [174]
3 years ago
14

The molar volume of oxygen,O2, is 3.90 dm3 mol-1 at 10.0 bar and 200 degree centigrade. Assuming that the expansion may be trunc

ated after the second term, calculate the second virial coefficient of oxygen at this temperature.
Chemistry
1 answer:
schepotkina [342]3 years ago
4 0

Answer:

B = - 0.0326 dm³/mol

Explanation:

virial eq until second term:

  • PVm = RT [ 1 + B/Vm ]

∴ P = 10 bar * (atm/ 1.01325 bar) = 9.869 atm

∴ T = 200°C = 473 K

∴ Vm = 3.90 dm³/mol

∴ R = 0.08206 dm³.atm/K.mol

⇒ PVm / RT = 1 + B/Vm

⇒ ((9.869 atm)*(3.90 dm³/mol)) / ((0.08206 dm³.atm/mol.K)*(473K)) = 1 + B/Vm

⇒ 0.99164 = 1 + B/Vm

⇒ B/Vm = - 8.357 E-3

⇒ B = (3.90 dm³/mol)*( - 8.357 E-3 )

⇒ B = - 0.0326 dm³/mol

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How many grams of magnesium acetate are in 8.95x10^23 formula units?
Natasha_Volkova [10]

Answer:

211.63 g.

Explanation:

  • Particles could refer to atoms, molecules, formula units.
  • <em>Knowing that every one mole of a substance contains Avogadro's no. of molecules (NA = 6.022 x 10²³).</em>

<em><u>Using cross multiplication:  </u></em>

1.0 mole → 6.022 x 10²³ molecules.

??? mole → 8.95 x 10²³ molecules.

  • The no. of moles of magnesium acetate = (8.95 x 10²³ molecules) (1.0 mole) / (6.022 x 10²³ molecules) = 1.486 mol.

∴ The grams of magnesium acetate are in 8.95 x 10²³ formula units = n x molar mass = (1.486 mol)(142.394 g/mol) = 211.63 g.

5 0
3 years ago
Consider two gases, A and B, are in a container at room temperature. What effect will the following changes have on the rate of
Tcecarenko [31]

Answer:

  1. decrease in temperature , decreases the kinetic movements of the gase molecules as a result decreases the frequency of collisions between gas molecules A and B consequently decreases the rate of reactions of gases A and B
6 0
2 years ago
If you have 16 g of manganese (II) nitrate tetrahydrate, how much water is required to prepare 0.16 M solution from this amount
nirvana33 [79]

<u>Answer:</u> The volume of water required is 398 mL

<u>Explanation:</u>

To calculate the molarity of solution, we use the equation:

\text{Molarity of the solution}=\frac{\text{Mass of solute}\times 1000}{\text{Molar mass of solute}\times \text{Volume of solution (in mL)}}

We are given:

Mass of solute (manganese (II) nitrate tetrahydrate) = 16 g

Molar mass of manganese (II) nitrate tetrahydrate = 251 g/mol

Molarity of solution = 0.16 M

Putting values in above equation, we get:

0.16M=\frac{16g\times 1000}{251g/mol\times \text{Volume of solution}}\\\\\text{Volume of solution}=398mL

Hence, the volume of water required is 398 mL

7 0
3 years ago
Calculate the molarity of the acid solution.<br>H2SO4(aq) with a pH of 2.
Lena [83]

Concentration "molarity" of H₂SO₄ in this solution:

5 × 10⁻³ mol / dm³.

<h3>Explanation</h3>

What's the concentration of H⁺ ions in this solution?

[\text{H}^{+}] = 10^{-\text{pH}},

where [\text{H}^{+}] is in the unit mol / dm³.

\text{pH} = 2

[\text{H}^{+}] = 10^{-2} \;\text{mol}\cdot\text{dm}^{-3}.

What's the concentration "molarity" of H₂SO₄ in this solution?

Sulfuric acid H₂SO₄ is a strong acid. Note the subscript "2". Each mole of this acid dissolves in water to produce two moles of H⁺ ions. It takes only \dfrac{10^{-2}}{2} = 5 \times 10^{-3}\;\text{mol}\cdot\text{dm}^{-3} of H₂SO₄ to produce twice as much H⁺ ions.

As a result, the <em>molarity</em> of H₂SO₄ is 5 × 10⁻³ mol / dm³ or 0.005 M.

3 0
3 years ago
The pressure in an automobile tire filled with air is 245.0 kPa. If Po2 = 51.3 kPa, Pco2 = 0.10 kPa, and P-others = 2.3 kPa, wha
Kay [80]

Answer:

PN₂ = 191.3 Kpa

Explanation:

Given data:

Total pressure of tire = 245.0 Kpa

Partial pressure of PO₂ = 51.3 Kpa

Partial pressure of PCO₂  = 0.10 Kpa

Partial pressure of others =  2.3 Kpa

Partial pressure of PN₂ = ?

Solution:

According to Dalton law of partial pressure,

The total pressure inside container is equal to the sum of partial pressures of individual gases present in container.

Mathematical expression:

P(total) = P₁ + P₂ + P₃+ ............+Pₙ

Now we will solve this  problem by using this law.

P(total) = PO₂ + PCO₂ + P(others)+ PN₂

245 Kpa = 51.3 Kpa + 0.10 Kpa + 2.3 Kpa + PN₂

245 Kpa = 53.7 Kpa+ PN₂

PN₂ = 245 Kpa -  53.7 Kpa

PN₂ = 191.3 Kpa

6 0
3 years ago
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