The molar volume of oxygen,O2, is 3.90 dm3 mol-1 at 10.0 bar and 200 degree centigrade. Assuming that the expansion may be trunc
ated after the second term, calculate the second virial coefficient of oxygen at this temperature.
1 answer:
Answer:
B = - 0.0326 dm³/mol
Explanation:
virial eq until second term:
∴ P = 10 bar * (atm/ 1.01325 bar) = 9.869 atm
∴ T = 200°C = 473 K
∴ Vm = 3.90 dm³/mol
∴ R = 0.08206 dm³.atm/K.mol
⇒ PVm / RT = 1 + B/Vm
⇒ ((9.869 atm)*(3.90 dm³/mol)) / ((0.08206 dm³.atm/mol.K)*(473K)) = 1 + B/Vm
⇒ 0.99164 = 1 + B/Vm
⇒ B/Vm = - 8.357 E-3
⇒ B = (3.90 dm³/mol)*( - 8.357 E-3 )
⇒ B = - 0.0326 dm³/mol
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