Answer:
A. for K>>1 you can say that the reaction is nearly irreversible so the forward direction is favored. (Products formation)
B. When the temperature rises the equilibrium is going to change but to know how is going to change you have to take into account the kind of reaction. For endothermic reactions (the reverse reaction is favored) and for exothermic reactions (the forward reaction is favored)
Explanation:
A. The equilibrium constant K is defined as
![K=\frac{Products}{reagents}](https://tex.z-dn.net/?f=K%3D%5Cfrac%7BProducts%7D%7Breagents%7D)
In any case
aA +Bb equilibrium Cd +dD
where K is:
![K= \frac{[C]^{c}[D]^{d}}{[A]^{a}[B]^{b}}](https://tex.z-dn.net/?f=K%3D%20%5Cfrac%7B%5BC%5D%5E%7Bc%7D%5BD%5D%5E%7Bd%7D%7D%7B%5BA%5D%5E%7Ba%7D%5BB%5D%5E%7Bb%7D%7D)
[] is molar concentration.
If K>>> 1 it means that the molar concentration of products is a lot bigger that the molar concentration of reagents, so the forward reaction is favored.
B. The relation between K and temperature is given by the Van't Hoff equation
![ln(\frac{K_{1}}{K_{2}})=\frac{-delta H^{o}}{R}*(\frac{1}{T_{1}}-\frac{1}{T_{2}})](https://tex.z-dn.net/?f=ln%28%5Cfrac%7BK_%7B1%7D%7D%7BK_%7B2%7D%7D%29%3D%5Cfrac%7B-delta%20H%5E%7Bo%7D%7D%7BR%7D%2A%28%5Cfrac%7B1%7D%7BT_%7B1%7D%7D-%5Cfrac%7B1%7D%7BT_%7B2%7D%7D%29)
Where: H is reaction enthalpy, R is the gas constant and T temperature.
Clearing the equation for
we get:
![K_{2}=\frac{K_{1}}{e^{\frac{-deltaH^{o}}{R}*(\frac{1}{T_{1}} -\frac{1}{T_{2}})}}](https://tex.z-dn.net/?f=K_%7B2%7D%3D%5Cfrac%7BK_%7B1%7D%7D%7Be%5E%7B%5Cfrac%7B-deltaH%5E%7Bo%7D%7D%7BR%7D%2A%28%5Cfrac%7B1%7D%7BT_%7B1%7D%7D%20-%5Cfrac%7B1%7D%7BT_%7B2%7D%7D%29%7D%7D)
Here we can study two cases: when delta
is positive (exothermic reactions) and when is negative (endothermic reactions)
For exothermic reactions when we increase the temperature the denominator in the equation would have a negative exponent so
is greater that
and the forward reaction is favored.
When we have an endothermic reaction we will have a positive exponent so
will be less than
the forward reactions is not favored.
![{e^{\frac{-deltaH^{o}}{R}*(\frac{1}{T_{1}} -\frac{1}{T_{2}})}}](https://tex.z-dn.net/?f=%7Be%5E%7B%5Cfrac%7B-deltaH%5E%7Bo%7D%7D%7BR%7D%2A%28%5Cfrac%7B1%7D%7BT_%7B1%7D%7D%20-%5Cfrac%7B1%7D%7BT_%7B2%7D%7D%29%7D%7D)
An example of erosion is the Grand Canyon, which was worn away over time by the Colorado river.
Balanced Half reactions are:
At anode 2
==> Cl₂+
+ H₂O ==>
+ 2
+
At Cathode: 2
+
==> H₂
Since the question states that you are using an aqueous solution of MnCl₂, so ions will have present are, H₂O,
,
and ![Cl^{-}](https://tex.z-dn.net/?f=Cl%5E%7B-%7D)
Now at Anode reaction will occur as given:
2
==> Cl₂+
+ H₂O ==>
+ 2
+
(will occur)
At Cathode:
2
+
==> H₂ (will occur)
At Cathode:
+
==> Mn (This reaction will not occur)
The deposition of solid Mn will not occur because in aqueous solution,
will be reduced before
.
The reduction potentials for
is zero whereas reduction potential for
is - 1.18V.
The reduction potential of a species is its tendency to gain electrons and get reduced. It is measured in millivolts or volts. Larger positive values of reduction potential are indicative of a greater tendency to get reduced.
To learn more about the half reaction please click on the link brainly.com/question/13186640
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Answer:
Step 1;
q = w = -0.52571 kJ, ΔS = 0.876 J/K
Step 2
q = 0, w = ΔU = -7.5 kJ, ΔH = -5.00574 kJ
Explanation:
The given parameters are;
= 100 N·m
= 327 K
= 90 N·m
Step 1
For isothermal expansion, we have;
ΔU = ΔH = 0
w = n·R·T·ln(
/
) = 1 × 8.314 × 600.15 × ln(90/100) = -525.71
w ≈<em> -0.52571</em> kJ
At state 1, q = w = -0.52571 kJ
ΔS = -n·R·ln(
/
) = -1 × 8.314 × ln(90/100) ≈ 0.876
ΔS ≈ 0.876 J/K
Step 2
q = 0 for adiabatic process
ΔU = 25×(27 - 327) = -7,500
w = ΔU = <em>-7.5 kJ</em>
ΔH = ΔU + n·R·ΔT
ΔH = -7,500 + 8.3142 × 300 = -5,005.74
ΔH = ΔU = <em>-5.00574 kJ</em>
The law of conservation of mass say that, in a chemical reaction, the mass of the reagents will always be equal to the mass of the products. This is shown in the reaction given below.
- Mass of the reagent: 100 g.
- Mass of the products: 56 + 44 = 100 g.