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The energy that is
essential to break one C-H bond is 414 kJ/mol. Since, there are four C-H bonds
in CH4, the energy Δ HCH4 for
breaking all the bonds is calculated as Δ HCH4 = 4 x bond energy of C-H bond. By
multiplying the 4 with the 414 kJ/mol you can get the answer of 1656 kJ/mol CH4
molecules.
The answer is dissolved in water, because in chemistry, (aq) is shorthand for aqueous solution.
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Atomic number, because the atomic number is unque to each individua element.