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VARVARA [1.3K]
3 years ago
9

. How many milliliters of 0.20 M HCl are needed to exactly neutralize 40. milliliters of 0.40 M KOH

Chemistry
1 answer:
Anuta_ua [19.1K]3 years ago
5 0

Answer:

V_{HCl}=80mL

Explanation:

Hello,

In this case, for the given reactants we identify the following chemical reaction:

KOH+HCl\rightarrow KCl+H_2O

Thus, we evidence a 1:1 molar ratio between KOH and HCl, therefore, for the complete neutralization we have equal number of moles, that in terms of molarities and volumes become:

n_{HCl}=n_{KOH}\\\\M_{HCl}V_{HCl}=M_{KOH}V_{KOH}

Hence, we compute the volume of HCl as shown below:

V_{HCl}=\frac{M_{KOH}V_{KOH}}{M_{HCl}} =\frac{0.40M*40mL}{0.20M} \\\\V_{HCl}=80mL

Best regards.

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Calculate the standard reaction Gibbs free energy for the following cell reactions: (a) 2 Ce41(aq) 1 3 I2(aq) S 2 Ce31(aq) 1 I32
Law Incorporation [45]

<u>Answer:</u>

<u>For a:</u> The standard Gibbs free energy of the reaction is -347.4 kJ

<u>For b:</u> The standard Gibbs free energy of the reaction is 746.91 kJ

<u>Explanation:</u>

Relationship between standard Gibbs free energy and standard electrode potential follows:

\Delta G^o=-nFE^o_{cell}           ............(1)

  • <u>For a:</u>

The given chemical equation follows:

2Ce^{4+}(aq.)+3I^{-}(aq.)\rightarrow 2Ce^{3+}(aq.)+I_3^-(aq.)

<u>Oxidation half reaction:</u>   Ce^{4+}(aq.)\rightarrow Ce^{3+}(aq.)+e^-       ( × 2)

<u>Reduction half reaction:</u>   3I^_(aq.)+2e^-\rightarrow I_3^-(aq.)

We are given:

n=2\\E^o_{cell}=+1.08V\\F=96500

Putting values in equation 1, we get:

\Delta G^o=-2\times 96500\times (+1.80)=-347,400J=-347.4kJ

Hence, the standard Gibbs free energy of the reaction is -347.4 kJ

  • <u>For b:</u>

The given chemical equation follows:

6Fe^{3+}(aq.)+2Cr^{3+}+7H_2O(l)(aq.)\rightarrow 6Fe^{2+}(aq.)+Cr_2O_7^{2-}(aq.)+14H^+(aq.)

<u>Oxidation half reaction:</u>   Fe^{3+}(aq.)\rightarrow Fe^{2+}(aq.)+e^-       ( × 6)

<u>Reduction half reaction:</u>   2Cr^{2+}(aq.)+7H_2O(l)+6e^-\rightarrow Cr_2O_7^{2-}(aq.)+14H^+(aq.)

We are given:

n=6\\E^o_{cell}=-1.29V\\F=96500

Putting values in equation 1, we get:

\Delta G^o=-6\times 96500\times (-1.29)=746,910J=746.91kJ

Hence, the standard Gibbs free energy of the reaction is 746.91 kJ

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3 years ago
A first-order decomposition reaction has a rate constant of 0.00440 yr−1. How long does it take for [reactant] to reach 12.5% of
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Answer:

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Explanation:

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Where,  

[A_t] is the concentration at time t

[A_0] is the initial concentration

Given:

To reach 12.5% of reactant means that 0.125 of [A_0] is decomposed. So,

\frac {[A_t]}{[A_0]} = 0.125

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Help! What did I do wrong??
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  <u><em>calculation</em></u>

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Step 1: find the moles  of sodium (Na)

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Step 2:use the mole ratio to determine  the  moles of H₂

  from  given equation  Na:H₂ is 2:1

therefore the moles  of H₂ = 2.117 moles x 1/2=1.059 moles

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According  to  Avogadro's  law  1 mole = 6.02 x 10²³ molecules

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