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inessss [21]
3 years ago
11

What is the value for ΔS°reaction for the following reaction, given the standard entropy values

Chemistry
2 answers:
Makovka662 [10]3 years ago
7 0
Standard entropy of the compounds of interest are as follows, 
S^{0} (C6H12O6) = 212.1 J/K.mol
S^{0} (O2) = 205.0 J/K.mol
S^{0} (CO2) = 213.6 J/K.mol
S^{0} (H2O) = 69.9 J/K.mol

Now for the reaction: 
<span>C6H12O6(s) + 6O2(g) —->6CO2(g) + 6H2O(l)
</span>
ΔS°reaction = ∑S^{0} products - ∑S^{0} reactants
∴ ΔS°reaction =( 6 S^{0} (CO2) + 6 S^{0} (H2O) ) - (S^{0} (C6H12O6) + 6 S^{0} (O2) = 205.0 J/K.mol)
∴ ΔS°reaction = [6 (213.6) + 6 (69.9 )] - [(212.1) + 6(205.0)]
∴ ΔS°reaction = 258.9 ≈ 262 J/ K mol.

Thus, correct answer is option C
lara [203]3 years ago
6 0
The answer is C. 262 J/ K mol.

Molar mass:
C6H12O6212.1 J/K.mol
O2= 205.0 J/K.mol
CO2 = 213.6 J/K.mol
H2O= 69.9 J/K.mol

THE BALANCE IS:
C6H12O6(s) + 6O2(g) —->6CO2(g) + 6H2O(l)

= [6 (213.6) + 6 (69.9 )] - [(212.1) + 6(205.0)]
= 258.9 
=262 J/ K mol.
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<u>Answer:</u> The mass percent of nitrogen gas and hydrogen gas is 91.41 % and 8.59 % respectively.

<u>Explanation:</u>

To calculate the number of moles, we use the equation given by ideal gas equation:

PV = nRT

where,

P = Pressure of the gaseous mixture = 1.00 atm

V = Volume of the gaseous mixture = 24.62 L

n = number of moles of the gaseous mixture = ?

R = Gas constant = 0.0821\text{ L atm }mol^{-1}K^{-1}

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Putting values in above equation, we get:

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We are given:

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Let the mass of nitrogen gas be 'x' grams and that of hydrogen gas be '(13.22 - x)' grams

To calculate the number of moles, we use the equation:

\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}

<u>For nitrogen gas:</u>

Molar mass of nitrogen gas = 28 g/mol

\text{Moles of nitrogen gas}=\frac{x}{28}mol

<u>For hydrogen gas:</u>

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\text{Moles of hydrogen gas}=\frac{(13.22-x)}{2}mol

Equating the moles of the individual gases to the moles of mixture:

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To calculate the mass percentage of substance in mixture we use the equation:

\text{Mass percent of substance}=\frac{\text{Mass of substance}}{\text{Mass of mixture}}\times 100

Mass of the mixture = 13.22 g

  • <u>For nitrogen gas:</u>

Mass of nitrogen gas = x = 12.084 g

Putting values in above equation, we get:

\text{Mass percent of nitrogen gas}=\frac{12.084g}{13.22g}\times 100=91.41\%

  • <u>For hydrogen gas:</u>

Mass of hydrogen gas = (13.22 - x) = (13.22 - 12.084) g = 1.136 g

Putting values in above equation, we get:

\text{Mass percent of hydrogen gas}=\frac{1.136g}{13.22g}\times 100=8.59\%

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