Freezing Point of Sea water would be lower than that of Pure Water. It is because of salinity of the water
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Q: What is the change of entropy for 3.0 kg of water when the 3.0 kg of water is changed to ice at 0 °C? (Lf = 3.34 x 105 J/kg)
Answer:
-3670.33 J/K
Explanation:
Entropy: This can be defined as the degree of randomness or disorderliness of a substance. The S.I unit of Entropy is J/K.
Mathematically, change of Entropy can be expressed as,
ΔS = ΔH/T ....................................... Equation 1
Where ΔS = Change of entropy, ΔH = heat change, T = temperature.
ΔH = -(Lf×m).................................... Equation 2
Note: ΔH is negative because heat is lost.
Where Lf = latent heat of ice = 3.34×10⁵ J/kg, m = 3.0 kg, m = mass of water = 3.0 kg
Substitute into equation
ΔH = -(3.34×10⁵×3.0)
ΔH = - 1002000 J.
But T = 0 °C = (0+273) K = 273 K.
Substitute into equation 1
ΔS = -1002000/273
ΔS = -3670.33 J/K
Note: The negative value of ΔS shows that the entropy of water decreases when it is changed to ice at 0 °C
They can all by seperrated or replicated.
Answer:
ΔS = -661.0J/mol is the entropy change for the system
ΔS = -842J/mol.K is the entropy change for the surroundings
Explanation:
From the relationship between ΔG, T, ΔH and ΔS,
Mathematically, ΔG = ΔH - TΔS
TΔS = ΔH - ΔS
ΔS = ΔH - ΔS / T
but ΔG = -54 kJ/mol, ΔH = -251 kJ/mol and T = 25 °C (298 K)
plugging into the equation,
ΔS = -251 kJ/mol - ( -54 kJ/mol) / 298
ΔS = -0.6610KJ/mol or in J.mol
ΔS = -661.0J/mol is the entropy change for the system
- For entropy change for the surroundings = ΔS = ΔH/T
- ΔS = -0.84KJ/mol.K or -842J/mol.K is the entropy change for the surroundings
