#19 due to weathering and erosion the rock from the stream was smoothened and without as much the rock from deep underground was/is very rugged and natural.
#18 Due to wind patterns the sand dunes are blew around and the sands shift and fly around with nothing to keep the sand in place the sand can go long distances or come long distances.
Answer:
B.Lone pair in pyrrolidine ring is localized and, therefore, is expected to be more reactive.
Explanation:
There are two nitrogen atoms bearing lone pairs of electrons in the structure of nicotine as shown in the image attached.
One nitrogen atom is found in the pyrrolidine ring. The lone pair on this nitrogen atom is localized hence it is more reactive than the lone pair of electrons found on the nitrogen atom in the pyridine ring which is delocalized a shown in the image attached to this answer.
Use the ideal gas law:
PV = nRT
so, T = PV / nR
n=0.5
V= 120 dm^3 = 120 L (1 dm^3 = 1 L)
R = 1/12
P = 15,000 Pa = 0.147 atm (1 pa = 9.86 10^{-6} )
Put the values:
T = PV / nR
T = (0.147) (120) / (0.5) (1/12)
T= 426 K