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qaws [65]
4 years ago
7

The temperature program for a separation starts at a temperature of 50 °C and ramps the temperature up to 270 °C at a rate of 10

°C/minute. Which statement is NOT true for this separation?
A) At 10 °C/minute, a total of 22 minutes is needed to reach 270 oC.
B) Strongly retained solutes will remain at the head of the column while the temperature is low.
C) Weakly retained solutes will separate and elute early in the separation.
D) The vapor pressure of strongly retained solutes will increase as temperature increases.
E) Strongly retained analytes will give broad peaks.
Chemistry
1 answer:
Troyanec [42]4 years ago
6 0

Answer:

The correct answer to the question is Option E (Strongly retained analytes will give broad peaks).

Explanation:

The other options are true because:

A. Initial temp = 50 °C

   Final temp =  270 °C

Differences in temp = 270 - 50 = 220°C

Rate =  10 °C/minute.

So, at 10 °C/minute,

total of 220°C /10 °C = number of minutes required to reach the final temp.

220/10 = 22 minutes

B. A column has a minimum and maximum use temperature. Solutes that are already retained would remain stationary while temperatures are low. This would only change if there is an increase in temperature. Heat transfers more energy to the liquid which would make the solute interact with the column phase.

C. Weakly retained solutes may contain larger molecules, will separate by absorbing into the solvent early in separation making the mobile phase separates out into its components on the stationary phase.

D. Retained solute's vapor pressure is higher at higher temperatures making it possible for particle to escape more from the solute when the temperature is high than when it is low.

You might be interested in
Calculate the following:
d1i1m1o1n [39]

Answer:

Explanation:

1) Given data:

Number of moles of lead = 4.3×10⁻³ mol

Mass of lead = ?

Solution:

Mass = number of moles × molar mass

Molar mass of lead = 207.2 g/mol

Mass = 4.3×10⁻³ mol × 207.2 g/mol

Mass =  890.96 g

2) Given data:

Number of atoms of antimony = 3.8×10²² atoms

Mass of antimony = ?

Solution:

1 mole contain 6.022 ×10²³ atoms

3.8×10²² atoms × 1 mol / 6.022 ×10²³ atoms

0.63×10⁻¹ mol

0.063 mol

Mass = number of moles × molar mass

Molar mass of lead = 121.76 g/mol

Mass = 0.063 mol ×  121.76 g/mol

Mass =  7.67 g

3) Given data:

Mass of tungsten = 15.5 Kg (15.5 kg × 1000 g/ 1kg = 15500 g)

Number of atoms = ?

Solution:

Number of moles of tungsten:

Number of moles = mass/molar mass

Number of moles = 15500 g / 183.84 g/mol

Number of moles = 84.3 mol

1 mole contain 6.022 ×10²³ atoms

84.3 mol  × 6.022 ×10²³ atoms / 1mol

507.65 ×10²³ atoms

8 0
3 years ago
For a particular reaction, ΔH⁰ = − 46.7 kJ/mol and ΔS⁰ = − 123.8 J / (mol ⋅ K). Assuming these values change very little with te
PilotLPTM [1.2K]

Answer:

T = 377.2 K, Less than

Explanation:

The thermodynamic quantity used in predicting whether a reaction is spontaneous or not is the gibbs free energy.

It's relationship with ΔH⁰ and ΔS⁰ is given as;

ΔG° = ΔH° - TΔS°

Basically, a negative value of ΔG° means the reaction is spontaeneous.

To obtain the calculated vale of T,

ΔS° = ΔH°/T

T = ΔH° / ΔS°

T = 377.2 K

Let's calculate the value of ΔG° at that temperature.

ΔG° = ΔH° - TΔS°

ΔG° =  − 46700 - 377.2(− 123.8)

ΔG°  = 0 (approximately, values are due to the rounding off)

At ΔG°  = 0 the reaction is at equilibrium.

To find if the reaction is spontaneous at lower or hugher temperature than the calculated temperature, we would be substituting the value of T with a smaller (random) value and also a larger (random) value.

Larger T (390K)

ΔG° = ΔH° - TΔS°

ΔG° =  − 46700 - 390(− 123.8)

ΔG°  = - 46700 + 48,282

ΔG° = 1582 J/mol

Smaller T (350K)

ΔG° = ΔH° - TΔS°

ΔG° =  − 46700 - 350(− 123.8)

ΔG°  = - 46700 + 43330

ΔG° = -3370J/mol

This means the temperature would be lesser than the calculated value for it to be spontaneus.

8 0
3 years ago
Consider the dissolution of calcium hydroxide:
Crazy boy [7]

Answer:

1. K_eq = [Ca^{2+][OH^-]^2 = K_{sp}

2. a. No effect;

b. Products;

c. Products;

d. Reactants

Explanation:

1. Equilibrium constant might be written using standard guidelines:

  • only aqueous species and gases are included in the equilibrium constant excluding solids and liquids;
  • the constant involves two parts: in the numerator of a fraction we include the product of the concentrations of products;
  • the denominator includes the product of the concentrations of reactants;
  • the concentrations are raised to the power of the coefficients in the balanced chemical equation.

Based on the guidelines, we have two ions on the product side, a solid on the left side. Thus, the equilibrium constant has the following expression:

K_eq = [Ca^{2+][OH^-]^2 = K_{sp}

2. a. In the following problems, we'll be considering the common ion effect. According to the principle of Le Chatelier, an increase in concentration of any of the ions would shift the equilibrium towards the formation of our precipitate.

In this problem, we're adding calcium carbonate. It is insoluble, so it wouldn't have any effect on the equilibrium.

b. Sodium carbonate is completely soluble, it would release carbonate ions. The carbonate ions would combine with calcium cations and more precipitate would dissolve. This would shift the equilibrium towards formation of the products to reproduce the amount of calcium cations.                                      

c. HCl would neutralize calcium hydroxide to produce calcium chloride and water, so the amount of calcium ions would increase, therefore, the products are favored.

d. NaOH contains hydroxide anions, so we'd have a common ion. An increase in hydroxide would produce more precipitate, so our reactants are favored.

3 0
3 years ago
When you live in a cold place and you're planning a vacation for February, are you interested in a location's weather or climate
Dahasolnce [82]

Answer:

It depends on what type of environment you are looking for. If you are looking for a warmer climate, warm weather and temperature is important. If you are looking for a cooler climate, you should look for colder weather and temperature. Humidity, geographical location, plant growth and foliage and elevation are also important when looking for a place to vacation.

Explanation:

5 0
3 years ago
Which of the following molecules contains a polar covalent bond?
Lady bird [3.3K]

Answer:

CO contains polar covalent bond, because these atoms share unequal electrons.

5 0
2 years ago
Read 2 more answers
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