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luda_lava [24]
3 years ago
7

For the reaction A+B+C→D+E, the initial reaction rate was measured for various initial concentrations of reactants. The followin

g data were collected: Trial [A] (M) [B] (M) [C] (M) Initial rate (M/s) 1 0.20 0.20 0.20 6.0×10−5 2 0.20 0.20 0.60 1.8×10−4 3 0.40 0.20 0.20 2.4×10−4 4 0.40 0.40 0.20 2.4×10−4For the reaction A+B+C -> D+E, the initial reaction rate was measured for various initial concentrations of reactants. The following data were collected:Trial [A] (M) [B[ (M) [C] (M) Initial rate (M/s)1 0.20 0.20 0.20 6.0 x 10^-52 0.20 0.20 0.60 1.8 x 10^-43 0.40 0.20 0.20 2.4 x 10^-44 0.40 0.40 0.20 2.4 x 10^-4Reaction order respect to A = 2Reaction order in respect to B = 0Reaction order in respect to C = 1The value of the rate constant k for this reaction = 7.5*10^-3 M^-2 * s^-1Given the data calculated in Parts A, B, C, and D, determine the initial rate for a reaction that starts with 0.75M of reagent A and 0.90M of reagents B and C?
Chemistry
1 answer:
erastovalidia [21]3 years ago
8 0

Answer : The initial rate for a reaction will be 3.4\times 10^{-3}Ms^{-1}

Explanation :

Rate law is defined as the expression which expresses the rate of the reaction in terms of molar concentration of the reactants with each term raised to the power their stoichiometric coefficient of that reactant in the balanced chemical equation.

For the given chemical equation:

A+B+C\rightarrow D+E

Rate law expression for the reaction:

\text{Rate}=k[A]^a[B]^b[C]^c

where,

a = order with respect to A

b = order with respect to B

c = order with respect to C

Expression for rate law for first observation:

6.0\times 10^{-5}=k(0.20)^a(0.20)^b(0.20)^c ....(1)

Expression for rate law for second observation:

1.8\times 10^{-4}=k(0.20)^a(0.20)^b(0.60)^c ....(2)

Expression for rate law for third observation:

2.4\times 10^{-4}=k(0.40)^a(0.20)^b(0.20)^c ....(3)

Expression for rate law for fourth observation:

2.4\times 10^{-4}=k(0.40)^a(0.40)^b(0.20)^c ....(4)

Dividing 1 from 2, we get:

\frac{1.8\times 10^{-4}}{6.0\times 10^{-5}}=\frac{k(0.20)^a(0.20)^b(0.60)^c}{k(0.20)^a(0.20)^b(0.20)^c}\\\\3=3^c\\c=1

Dividing 1 from 3, we get:

\frac{2.4\times 10^{-4}}{6.0\times 10^{-5}}=\frac{k(0.40)^a(0.20)^b(0.20)^c}{k(0.20)^a(0.20)^b(0.20)^c}\\\\4=2^a\\a=2

Dividing 3 from 4, we get:

\frac{2.4\times 10^{-4}}{2.4\times 10^{-4}}=\frac{k(0.40)^a(0.40)^b(0.20)^c}{k(0.40)^a(0.20)^b(0.20)^c}\\\\1=2^b\\b=0

Thus, the rate law becomes:

\text{Rate}=k[A]^2[B]^0[C]^1

Now, calculating the value of 'k' by using any expression.

Putting values in equation 1, we get:

6.0\times 10^{-5}=k(0.20)^2(0.20)^0(0.20)^1

k=7.5\times 10^{-3}M^{-2}s^{-1}

Now we have to calculate the initial rate for a reaction that starts with 0.75 M of reagent A and 0.90 M of reagents B and C.

\text{Rate}=k[A]^2[B]^0[C]^1

\text{Rate}=(7.5\times 10^{-3})\times (0.75)^2(0.90)^0(0.90)^1

\text{Rate}=3.4\times 10^{-3}Ms^{-1}

Therefore, the initial rate for a reaction will be 3.4\times 10^{-3}Ms^{-1}

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Answer:

24.24 L

Explanation:

Boyle’s law, also called Mariotte’s law, a relation concerning the compression and expansion of a gas at constant temperature.

This empirical relation, formulated by the physicist Robert Boyle in 1662, states that the pressure (p) of a given quantity of gas varies inversely with its volume (v) at constant temperature; i.e., in equation form, pv = k, a constant.

Real gases obey Boyle’s law at sufficiently low pressures, although the product pv generally decreases slightly at higher pressures, where the gas begins to depart from ideal behaviour.

As, PV = k

P₁ V₁ = P₂ V₂

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V₁ = 6 L

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The mass of an electron is 9.11× 10–31 kg. What is the uncertainty in the position of an electron moving at 2.00 × 106 m/s with
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A compound containing Na, C, and O is found to have 1.06 mol Na, 0.528 mol C, and 1.59 mol O. What is the empirical formula of t
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Given :

Moles of Na : 1.06

Moles of C : 0.528

Moles of O : 1.59

To Find :

The empirical formula of the compound.

Solution :

Dividing moles of each atom with the smallest one i.e 0.528 .

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O : 1.59/0.528 = 3.011 ≈ 3

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So, empirical formula is Na_2CO_3 .

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