Much like a battery, wood contains stored energy. What energy transformations occur when wood is burned?

What happens to the molecules when you heat a solid

Elena-2011 [213]

The molecules vibrate faster and space between atoms increase

8 0

3 years ago

or a particular isomer of C 8 H 18 , the combustion reaction produces 5104.1 kJ of heat per mole of C 8 H 18 ( g ) consumed, und

beks73 [17]

Answer:

The standard enthalpy of formation of this isomer of $C_{8}H_{18}$ is -220.1 kJ/mol.

Explanation:

The given chemical reaction is as follows.

$C_{8}H_{18}(g)+ \frac{25}{2}O_{2}(g) \rightarrow 8CO_{2}(g)+9H_{2}O(g)$

$\Delta H^{o}_{rxn}= -5104.1kJ/mol$

The expression for the entropy change for the reaction is as follows.

$\Delta H^{o}_{rxn}=[8\Delta H^{o}_{f}(CO_{2}) +9\Delta H^{o}_{f}(H_{2}O)]-[\Delta H^{o}_{f}(C_{8}H_{18})+ \frac{25}{2}\Delta H^{o}_{f}(O_{2})]$

$\Delta H^{o}_{f}(H_{2}O)= -241.8kJ/mol$

$\Delta H^{o}_{f}(CO_{2})= -393.5kJ/mol$

$\Delta H^{o}_{f}(O_{2})= 0kJ/mol$

Substitute the all values in the entropy change expression.

$-5104.1kJ/mol=[8(-393.5)+9(-241.8)kJ/mol]-[\Delta H^{o}_{f}(C_{8}H_{18})+ \frac{25}{2}(0)kJ/mol]$

$-5104.1kJ/mol=-5324.2kJ/mol -\Delta H^{o}_{f}(C_{8}H_{18})$

$\Delta H^{o}_{f}(C_{8}H_{18}) =-5324.2kJ/mol +5104.1kJ/mol$

$=-220.1kJ/mol$

Therefore, The standard enthalpy of formation of this isomer of $C_{8}H_{18}$ is -220.1 kJ/mol.

4 0

3 years ago

KFell Fe"(CN), + e + Nat → KNaFe'Fe(CN)6

Alinara [238K]

Answer:

Most common oxidation states: +2, +3

M.P. 1535º

B.P. 2750º

Density 7.87 g/cm3

Characteristics: Iron is a gray, moderately active metal.

Characteristic reactions of Fe²⁺ and Fe³⁺

The [Fe(H2O)6]3+ ion is colorless (or pale pink), but many solutions containing this ion are yellow or amber-colored because of hydrolysis. Iron in both oxidation states forms many complex ions.

Aqueous Ammonia

Aqueous ammonia reacts with Fe(II) ions to produce white gelatinous Fe(OH)2, which oxidizes to form red-brown Fe(OH)3:

Fe2+(aq)+2NH3(aq)+3H2O(l)↽−−⇀Fe(OH)2(s)+2NH+4(aq)(1)

Fe3appt.gif

Aqueous ammonia reacts with Fe(III) ions to produce red-brown Fe(OH)3:

Fe3+(aq)+3NH3(aq)+3H2O(l)↽−−⇀Fe(OH)3(s)+3NH+4(aq)(2)

Fe3bppt.gif

Both precipitates are insoluble in excess aqueous ammonia. Iron(II) hydroxide quickly oxidizes to Fe(OH)3 in the presence of air or other oxidizing agents.

Sodium Hydroxide

Sodium hydroxide also produces Fe(OH)2 and Fe(OH)3 from the corresponding oxidation states of iron in aqueous solution.

Fe2+(aq)+2OH−(aq)↽−−⇀Fe(OH)2(s)(3)

Fe4appt.gif

Fe3+(aq)+3OH−(aq)↽−−⇀Fe(OH)3(s)(4)

Fe4bppt.gif

Neither hydroxide precipitate dissolves in excess sodium hydroxide.

Potassium Ferrocyanide

Potassium ferrocyanide will react with Fe3+ solution to produce a dark blue precipitate called Prussian blue:

K+(aq)+Fe3+(aq)+[Fe(CN)6]4−(aq)↽−−⇀KFe[Fe(CN)6](s)(5)

Fe5a1ppt.gif

With Fe2+ solution, a white precipitate will be formed that will be converted to blue due to the oxidation by oxygen in air:

2Fe2+(aq)+[Fe(CN)6]4−(aq)↽−−⇀Fe2[Fe(CN)6](s)(6)

Fe5a2ppt.gif

Many metal ions form ferrocyanide precipitates, so potassium ferrocyanide is not a good reagent for separating metal ions. It is used more commonly as a confirmatory test.

Potassium Ferricyanide

Potassium ferricyanide will give a brown coloration but no precipitate with Fe3+. With Fe2+, a dark blue precipitate is formed. Although this precipitate is known as Turnbull's blue, it is identical with Prussian blue (from Equation 5).

K+(aq)+Fe+2(aq)+[Fe(CN)6]3−(aq)↽−−⇀KFe[Fe(CN)6](s)(7)

Fe5b.gif

Potassium Thiocyanate

KSCN will give a deep red coloration to solutions containing Fe3+:

Fe+3(aq)+NCS−(aq)↽−−⇀[FeNCS]+2(aq)(8)

Fe5cppt.gif

No Reaction

Cl−, SO2−4

7 0

3 years ago

Nitrogen ion (Nitride) is ... Cation/Anion/Neither? # of protons? # of electrons? Charge (1-, 2-, 3-, 1+, 2+, 3+, or 0) Number o

OLga [1]

Answer:

3- is the charge and 8 dots on its Lewis dot structure.

Explanation:

Hello there!

In this case, since nitrogen is an element with five valence electrons (electrons on its outer shell), we infer that it needs three bonds to complete the octet, for which its charge, when forming nitride ions is 3-, which means it has received three electrons. Thus, when drawing the Lewis dot structure, it is evident that is will have 5+3 = 8 dots due to the electron reception.

Regards!

8 0

3 years ago

What is the volume in liters of 3.39 kg of ethylene glycol?

Sergeu [11.5K]

<span>The volume in liters is </span>v=3.7xL

4 0

3 years ago