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3 years ago

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When gases are treated as real, via use of the van der Waals equation, the actual volume occupied by gas molecules ________ the

pressure exerted and the attractive forces between gas molecules ________ the pressure exerted, as compared to an ideal gas.
decreases, increases
does not affect, decreases
increases, decreases
does not affect, increases
increases, increases

1 answer:

Tresset [83]3 years ago

6 0

Answer:

Increases, decreases

Explanation:

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First we have to calculate the heat gained by the calorimeter.

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$\Delta H=-\frac{23.4kJ}{0.00834mole}=-2805.8kJ/mole$

Therefore, the enthalpy change during the reaction is -2805.8 kJ/mole

Now we have to calculate the internal energy change for the combustion of 1.501 g of fructose.

Formula used :

$\Delta H=\Delta U+\Delta n_gRT$

or,

$\Delta U=\Delta H-\Delta n_gRT$

where,

$\Delta H$ = change in enthalpy = $-2805.8kJ/mol$

$\Delta U$ = change in internal energy = ?

$\Delta n_g$ = change in moles = 0 (from the reaction)

R = gas constant = 8.314 J/mol.K

T = temperature = $27.43^oC=273+27.43=300.43K$

Now put all the given values in the above formula, we get:

$\Delta U=\Delta H-\Delta n_gRT$

$\Delta U=(-2805.8kJ/mol)-[0mol\times 8.314J/mol.K\times 300.43K$

$\Delta U=-2805.8kJ/mol-0$

$\Delta U=-2805.8kJ/mol$

Therefore, the internal energy change is -2805.8 kJ/mol

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