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Answer:
a)
⇒
⇒
b)
⇒
⇒
Explanation:
A)
Remember that positive number superscripts mean electrons lack and negative numbers mean electrons 'excess' (if we compare it with the neutral element). So, for the case of Fe2+ which is converted to Fe3+, we know that in Fe2+ there is a two electrons lack, while in Fe3+ there is a 3 electrons lack; it means that Fe2+ was converted to Fe3+ but releasing one electron:
⇒
The same analysis is applied to Br2; Br2 is a molecule which is said to have a zero superscript because it is an apolar covalent bond; and it is converted to Br-, which, according to what I wrote above, means that there is a one electron excess. So, Br2 must have received an electron in order to change to Br-; but Br2 can't change to Br- as simple as that because Br2 is a molecule, not an atom; it is a molecule that has two Br atoms, so, Br2 must give two Br- ions as products, but receiving one electron for each one:
⇒
b)
Applying the same, in Mg2+ there is a 2 electrons lack, and in Mg is not electron lack (its superscript is zero), so Mg must have released two electrons in order to change to Mg2+:
⇒
Cr3+ has a 3 electrons lack, and Cr2+ a two electrons one, so, Cr3+ must receive an electron to convert to Cr2+:
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Answer:
A) 1059 J/mol
B) 17,920 J/mol
Explanation:
Given that:
Cp = 29.42 - (2.170*10^-3 ) T + (0.0582*10^-5 ) T2 + (1.305*10^-8 ) T3 – (0.823*10^-11) T4
R (constant) = 8.314
We know that:
We can determine from above if we make
the subject of the formula as:
A).
The formula for calculating change in internal energy is given as:
If we integrate above data into the equation; it implies that:
Hence, the internal energy that must be added to nitrogen in order to increase its temperature from 450 to 500 K = 1059 J/mol.
B).
If we repeat part A for an initial temperature of 273 K and final temperature of 1073 K.
then T = 273 K & T2 = 1073 K
∴