SiO2 is the only possible choice because the other formulas contain metals. how do we know this? because the other formulas contain elements located on the left of the “staircase” on the periodic table that separates metals from non-metals.
You slap some dough on to a beach and wait for it to become bread
Answer:
10.64
Explanation:
Let's consider the basic reaction of cyclohexamine, C₆H₁₁NH₂.
C₆H₁₁NH₂(aq) + H₂O(l) ⇄ C₆H₁₁NH₃⁺(aq) + OH⁻ pKb = 3.36
C₆H₁₁NH₃⁺ is its conjugate acid, since it donates H⁺ to form C₆H₁₁NH₂. C₆H₁₁NH₃⁺ acid reaction is as follows:
C₆H₁₁NH₃⁺(aq) + H₂O(l) ⇄ C₆H₁₁NH₂(aq) + H₃O⁺(aq) pKa
We can find the pKa of C₆H₁₁NH₃⁺ using the following expression.
pKa + pKb = 14.00
pKa = 14.00 - pKb = 14.00 - 3.36 = 10.64
The molarity of formic acid is 100 mM or 
. The dissociation reaction of formic acid is as follows:
The expression for dissociation constant of the reaction will be:
![K_{a}=\frac{[HCOO^{-}][H^{+}]}{[HCOOH]}](https://tex.z-dn.net/?f=K_%7Ba%7D%3D%5Cfrac%7B%5BHCOO%5E%7B-%7D%5D%5BH%5E%7B%2B%7D%5D%7D%7B%5BHCOOH%5D%7D)
Rearranging,
![[HCOO^{-}]=\frac{K_{a}[HCOOH]}{[H^{+}]}](https://tex.z-dn.net/?f=%5BHCOO%5E%7B-%7D%5D%3D%5Cfrac%7BK_%7Ba%7D%5BHCOOH%5D%7D%7B%5BH%5E%7B%2B%7D%5D%7D)
Here, pH of solution is 4.15 thus, concentration of hydrogen ion will be:
![[H^{+}]=10^{-pH}=10^{-4.15}=7.08\times 10^{-5}M](https://tex.z-dn.net/?f=%5BH%5E%7B%2B%7D%5D%3D10%5E%7B-pH%7D%3D10%5E%7B-4.15%7D%3D7.08%5Ctimes%2010%5E%7B-5%7DM)
Similarly, 
thus,
Putting the values,
![[HCOO^{-}]=\frac{(1.78\times 10^{-4}M)(100\times 10^{-3}M)}{(7.08\times 10^{-5}M}=0.2511 M](https://tex.z-dn.net/?f=%5BHCOO%5E%7B-%7D%5D%3D%5Cfrac%7B%281.78%5Ctimes%2010%5E%7B-4%7DM%29%28100%5Ctimes%2010%5E%7B-3%7DM%29%7D%7B%287.08%5Ctimes%2010%5E%7B-5%7DM%7D%3D0.2511%20M)
Therefore, the concentration of formate will be 0.2511 M.
