A reaction occurs in which hydrogen-1 and hydrogen-2 form helium-3. Is this a chemical reaction or a nuclear reaction, and how d
1 answer:
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Enthalpy change is the difference between energy used and energy gained. The change in enthalpy of the liquid mercury is 0.0231 kJ.
<h3>What is the enthalpy change?</h3>Enthalpy change is the difference between the energy used to break chemical bonds and the energy gained by the products formed in a chemical reaction.
The enthalpy change is given by,
and,
Given,
Mass of the liquid mercury (m) = 11.0 gm
The specific heat of mercury (c) = 0.14 J per g per degree Celsius
Temperature change = 15 degrees Celsius
Enthalpy change is calculated as:
Therefore, 0.0231 kJ is the change in enthalpy.
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Answer : The correct option is, +91 kJ/mole
Solution :
The balanced cell reaction will be,
Here copper (Cu) undergoes oxidation by loss of electrons, thus act as anode. Lead (Pb) undergoes reduction by gain of electrons and thus act as cathode.
First we have to calculate the standard electrode potential of the cell.
Now we have to calculate the standard Gibbs free energy.
Formula used :
where,
= standard Gibbs free energy = ?
n = number of electrons = 2
F = Faraday constant = 96500 C/mole
= standard e.m.f of cell = -0.47 V
Now put all the given values in this formula, we get the Gibbs free energy.
Therefore, the standard Gibbs free energy is +91 kJ/mole