Explanation:
The reaction given is;
TiCl4 + H2O --> TiO2 + HCl
The reaction is not balanced, upon balancing it is given as;
TiCl4 + 2H2O → TiO2 + 4HCl
a. How many moles of H2O are needed to react with 6.50 moles of TiCl4?
From the reaction;
1 mol of TiCl4 requires 2 mol of H2O
6.50 mol of TiCl4 would require x mol of H2O
1 = 2
6.5 = x
x = 6.5 * 2 / 1 = 13.0 mol
b. How many moles of HCl are formed when 8.44 moles of TiCl4 react?
From the equation of the reaction;
1 mol of TiCl4 reacts to form 4 mol of HCl
8.44 mol of TiCl4 reacts to form x mol of HCl
1 = 4
8.44 = x
x = 8.44 * 4 / 1 = 33.76 mol
It takes 33.4 s for the concentration of A to fall to one-fourth of its original value.
A <em>half-life</em> is the time it takes for the concentration to fall to half its original value.
Assume the initial concentration is 1.00 mol/L. Then,

The concentration drops to one-fourth of its initial value in two half-lives.
∴ Time = 2 × 16.7 s = 33.4 s
Answer:
II
Explanation:
We must have a good idea of the fact that there are two mechanisms that come into play when we are discussing about the addition of hydrogen halides to alkenes. The first is the ionic mechanism and the second is the radical mechanism.
The ionic mechanism is accounted for by the Markovnikov rule while the radical mechanism occurs in the presence of peroxides and is generally referred to as anti Markovnikov addition.
The intermediate in anti Markovnikov addition involves the most stable radical, in this case, it is a tertiary radical as shown in the images attached. The most stable radical is II hence it leads to the major product shown in the other image.