Answer:
1. The dye that absorbs at 530 nm.
Explanation:
The dye will absorb light to promote the transition of an electron from the HOMO to the LUMO orbital.
The higher the gap, the higher the energy of transition. The energy can be calculated by E = hc/λ, in which h and c are constants and λ is the wavelength.
The equation shows that the higher the energy, the higher the gap and the lower the wavelength.
Therefore, the dye with absorption at 530 nm has the higher HOMO-LUMO gap.
Reactives
-> Products
CuO
and water are products.
I
found this reaction which has CuO and water as products: decomposition of
Cu(OH)2.
Cu(OH)2
-> CuO + H2O
Stoichiometry calculus involve the mole
proportions you can see in the reaction: When 1 mole of Cu(OH)2 reacts, 1 mole of
CuO and 1 mole of H2O are formed.
Considering
the molar masses:
Cu(OH)2
= 83.56 g/mol
CuO
= 79.545 g/mol
H2O
= 18.015 g/mol
Then:
When 83.56 g of Cu(OH)2 react, 79.545 g of CuO and 18.015 g H2O are formed.
You
should use that numbers in the rule of three:
79.545
g CuO __________18.015 g water
3.327
g CuO__________ x =3.327*18.015 /79.545 g water
x= 0.7535 g water
Answer : The balanced equations will be:
Explanation :
The general rate of reaction is,
Rate of reaction : It is defined as the change in the concentration of any one of the reactants or products per unit time.
The expression for rate of reaction will be :
![\text{Rate of disappearance of A}=-\frac{1}{a}\frac{d[A]}{dt}](https://tex.z-dn.net/?f=%5Ctext%7BRate%20of%20disappearance%20of%20A%7D%3D-%5Cfrac%7B1%7D%7Ba%7D%5Cfrac%7Bd%5BA%5D%7D%7Bdt%7D)
![\text{Rate of disappearance of B}=-\frac{1}{b}\frac{d[B]}{dt}](https://tex.z-dn.net/?f=%5Ctext%7BRate%20of%20disappearance%20of%20B%7D%3D-%5Cfrac%7B1%7D%7Bb%7D%5Cfrac%7Bd%5BB%5D%7D%7Bdt%7D)
![\text{Rate of formation of C}=+\frac{1}{c}\frac{d[C]}{dt}](https://tex.z-dn.net/?f=%5Ctext%7BRate%20of%20formation%20of%20C%7D%3D%2B%5Cfrac%7B1%7D%7Bc%7D%5Cfrac%7Bd%5BC%5D%7D%7Bdt%7D)
![\text{Rate of formation of D}=+\frac{1}{d}\frac{d[D]}{dt}](https://tex.z-dn.net/?f=%5Ctext%7BRate%20of%20formation%20of%20D%7D%3D%2B%5Cfrac%7B1%7D%7Bd%7D%5Cfrac%7Bd%5BD%5D%7D%7Bdt%7D)
![Rate=-\frac{1}{a}\frac{d[A]}{dt}=-\frac{1}{b}\frac{d[B]}{dt}=+\frac{1}{c}\frac{d[C]}{dt}=+\frac{1}{d}\frac{d[D]}{dt}](https://tex.z-dn.net/?f=Rate%3D-%5Cfrac%7B1%7D%7Ba%7D%5Cfrac%7Bd%5BA%5D%7D%7Bdt%7D%3D-%5Cfrac%7B1%7D%7Bb%7D%5Cfrac%7Bd%5BB%5D%7D%7Bdt%7D%3D%2B%5Cfrac%7B1%7D%7Bc%7D%5Cfrac%7Bd%5BC%5D%7D%7Bdt%7D%3D%2B%5Cfrac%7B1%7D%7Bd%7D%5Cfrac%7Bd%5BD%5D%7D%7Bdt%7D)
From this we conclude that,
In the rate of reaction, A and B are the reactants and C and D are the products.
a, b, c and d are the stoichiometric coefficient of A, B, C and D respectively.
The negative sign along with the reactant terms is used simply to show that the concentration of the reactant is decreasing and positive sign along with the product terms is used simply to show that the concentration of the product is increasing.
Now we have to determine the balanced equations corresponding to the following rate expressions.
![Rate=-\frac{d[CH_4]}{dt}=-\frac{1}{2}\frac{d[O_2]}{dt}=+\frac{1}{2}\frac{d[H_2O]}{dt}=+\frac{d[CO_2]}{dt}](https://tex.z-dn.net/?f=Rate%3D-%5Cfrac%7Bd%5BCH_4%5D%7D%7Bdt%7D%3D-%5Cfrac%7B1%7D%7B2%7D%5Cfrac%7Bd%5BO_2%5D%7D%7Bdt%7D%3D%2B%5Cfrac%7B1%7D%7B2%7D%5Cfrac%7Bd%5BH_2O%5D%7D%7Bdt%7D%3D%2B%5Cfrac%7Bd%5BCO_2%5D%7D%7Bdt%7D)
The balanced equations will be:
