Answer:
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a. 381.27 m/s
b. the rate of effusion of sulfur dioxide = 2.5 faster than nitrogen triiodide
<h3>Further explanation</h3>
Given
T = 100 + 273 = 373 K
Required
a. the gas speedi
b. The rate of effusion comparison
Solution
a.
Average velocities of gases can be expressed as root-mean-square averages. (V rms)
R = gas constant, T = temperature, Mm = molar mass of the gas particles
From the question
R = 8,314 J / mol K
T = temperature
Mm = molar mass, kg / mol
Molar mass of Sulfur dioxide = 64 g/mol = 0.064 kg/mol
b. the effusion rates of two gases = the square root of the inverse of their molar masses:
M₁ = molar mass sulfur dioxide = 64
M₂ = molar mass nitrogen triodide = 395
the rate of effusion of sulfur dioxide = 2.5 faster than nitrogen triodide
Method 1: gravimetry
advantages: Impurities in the sample can be identified
disadvantages: The process is long, because it goes through several stages
Method 2: titration
advantages: the process is fast, because the titrate and titrant react immediately
disadvantages: Sometimes the determination of the end point of the titration is carried out too fast or too slowly so that the calculations carried out are inaccurate
Answer is: Kb for methylamine is 4.37·10⁻⁴.<span>
Chemical reaction: CH</span>₃NH₂ + H₂O → CH₃NH₃⁺ + OH⁻.
c(CH₃NH₂) = 0.253 M.
α = 4.07% ÷ 100% = 0.0407.
[CH₃NH₃⁺] = [OH⁻] = c(CH₃NH₂) · α.
[CH₃NH₃⁺] = [OH⁻] = 0.253 M · 0.0407.
[CH₃NH₃⁺] = [OH⁻] = 0.0103 M.
[CH₃NH₂] = 0.253 M - 0.0103 M.
[CH₃NH₂] = 0.2427 M.
Kb = [CH₃NH₃⁺] · [OH⁻] / [CH₃NH₂].
Kb = (0.0103 M)² / 0.2427 M.
Kb = 4.37·10⁻⁴.
