An unknown compound displays singlets at δ 2.1 ppm and 2.56 ppm in the ratio of 3:2. what is the structure of the compound?
1 answer:
1) As can be seen from any 1H NMR chemical shift ppm tables, hydrogens which have δ values from 2ppm to 2.3ppm are hydrogens from carbon which is bonded to a carbonyl group. From this, we can conclude that our hydrogens belong to the type, but from 2 different alkyl groups because of 2 different signals.
2) So, one alkyl group is CH3 and second one can be CH or CH2.
3) If we know that ratio between two types of hydrogens is 3:2, it can be concluded that second alkyl group is CH2.
4) Finally, we don't have any other signals and it indicates that part of the compound which continues on CH2 is exactly the same as the first part.
The ratio remains the same, 3:2 ie 6:4
You might be interested in
Answer:
The concentration of the resulting solution in parts per million is 177.97
Explanation:
Parts per million (ppm), is a unit of measure for concentration that refers to the number of units of the substance per million units of the set.
The concentration in parts per million expressed in mass / mass is calculated by dividing the mass of the solute (ms) by the mass of the solution (md, sum of the mass of the solute and the mass of the solvent), both expressed in the same unit and multiplied by 10⁶ (1 million).
So, being:
- ms: 0.089 grams of KI
- md: 0.089 grams of KI + 500 grams of H₂O= 500.089 grams
Replacing:
ppm= 177.97
<u><em>The concentration of the resulting solution in parts per million is 177.97</em></u>