Answer:
Explanation:
a).
conc of Ca²⁺ =0.0025 M
pCa = -log(0.0025) = 2.6
logK,= 10.65 So lc = 4.47 x 10.
Formation constant of Ca(EDTA)]-z= 4.47 x 10¹⁰ At pH = 11, the fraction of EDTA that exists Y⁻⁴ is
=0.81
So the Conditional Formation constant=
=0.81x 4.47 x10¹⁰
=3.62x10¹⁰
b)
At Equivalence point:
Ca²⁺ forms 1:1 complex with EDTA At equivalence point,
Number of moles of Ca²⁺= Number of moles of EDTA Number of moles of Ca²⁺ = M×V = 0.00250 M × 50.00 mL = 0.125 mol
Number of moles of EDTA= 0.125 mol
Volume of EDTA required = moles/Molarity = 0.125 mol / 0.0050 M = 25.00 mL
V e= 25.00 mL
At equivalence point, all Ca²⁺ is converted to [CaY²⁻] complex. So the concentration of Ca²⁺ is determined by the dissociation of [CaY²⁻] complex.
![[CaY^{2-}] = \frac{Initial,moles,of, Ca^{2+}}{Total,Volume} = \frac{0.125mol}{(50.00+25.00)mL} = 0.001667M](https://tex.z-dn.net/?f=%5BCaY%5E%7B2-%7D%5D%20%3D%20%5Cfrac%7BInitial%2Cmoles%2Cof%2C%20Ca%5E%7B2%2B%7D%7D%7BTotal%2CVolume%7D%20%3D%20%5Cfrac%7B0.125mol%7D%7B%2850.00%2B25.00%29mL%7D%20%3D%200.001667M)

Ca²⁺ + Y⁴ ⇄ CaY²⁻
Initial 0 0 0.001667
change +x +x -x
equilibrium x x 0.001667 - x
![{K^'}_f = \frac{[CaY^{2-}]}{[Ca^{2+}][Y^4]}=\frac{0.001667-x}{x.x} =\frac{0.001667-x}{x^2}\\\\x^2 = \frac{0.001667-x}{{K^'}_f}\\ \\](https://tex.z-dn.net/?f=%7BK%5E%27%7D_f%20%3D%20%5Cfrac%7B%5BCaY%5E%7B2-%7D%5D%7D%7B%5BCa%5E%7B2%2B%7D%5D%5BY%5E4%5D%7D%3D%5Cfrac%7B0.001667-x%7D%7Bx.x%7D%20%3D%5Cfrac%7B0.001667-x%7D%7Bx%5E2%7D%5C%5C%5C%5Cx%5E2%20%3D%20%5Cfrac%7B0.001667-x%7D%7B%7BK%5E%27%7D_f%7D%5C%5C%20%5C%5C)

x = 2.15×10⁻⁷
[Ca+2] = 2.15x10⁻⁷ M
pca = —log(2 15x101= 6.7
Answer:
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Explanation:
the force between the electron and the proton.
a) Use F = k * q1 * q2 / d²
where k = 8.99e9 N·m²/C²
and q1 = -1.602e-19 C (electron)
and q2 = 1.602e-19 C (proton)
and d = distance between point charges = 0.53e-10 m
The negative result indicates "attraction".
the radial acceleration of the electron.
b) Here, just use F = ma
where F was found above, and
m = mass of electron = 9.11e-31kg, if memory serves
a = radial acceleration
the speed of the electron.
c) Now use a = v² / r
where a was found above
and r was given
<span> the period of the circular motion.</span>
d) period T = 2π / ω = 2πr / v
where v was found above
and r was given
The most stable conformation of
trans-1-tert-butyl-2-methylcyclohexane is the one in which both the
tert-butyl group and the methyl group are located near the equatorial position.
Trans conformation are usually stable at the equatorial position to avoid the
bulkyl group ( the tert-butyl group and methyl group) be together to reduce the
so called Steric hindrance.
Answer:
The answer is "
"
Explanation:
When
is added in the chemical equation it reacts with sodium acetate so, it will give the following chemical equation:
In this, the
is a weak acid so, it not completely dissociated.
were strong electrolytes they are completely dissociated.
The
is a strong acid so, it is completely dissociated So, the net ionic equation is:
