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The volume of the buffer solution having a ph value is calculated by henderson's hasselbalch equation.
Buffer solution is water based solution which consists of a mixture containing a weak acid and a conjugate base of the weak acid. or a weak base and conjugate acid of a weak base.it is a mixture of weak acid and a base. The pH of the buffer solution is determined by the expression of the henderson hasselbalch equation.
pH=pKa + log [salt]/[acid]
Where, pKa =dissociation constant , A- = concentration of the conjugate base, [HA]= concentration of the acid. Here, a buffer solution contains 0.403m acetic acid and 250 ml is added in order to prepare a buffer with a ph of 4.750. Putting all the values in the henderson hasselbalch equation we find the pH of the buffer solution.
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Answer:
1.62
Explanation:
From the given information:
number of moles of benzamide 
= 0.58 mole
The molality = 

= 0.6837
Using the formula:

where;
dT = freezing point = 27
l = Van't Hoff factor = 1
kf = freezing constant of the solvent
∴
2.7 °C = 1 × kf × 0.6837 m
kf = 2.7 °C/ 0.6837m
kf = 3.949 °C/m
number of moles of NH4Cl = 
= 1.316 mol
The molality = 
= 1.5484
Thus;
the above kf value is used in determining the Van't Hoff factor for NH4Cl
i.e.
9.9 = l × 3.949 × 1.5484 m

l = 1.62
Answer:
Just think of whats in a forest ecosystem
for example
Water
sunlight
tempreture