Answer:
D) the carbon with the low-energy phosphate on it in 1,3 BPG is labeled.
Explanation:
Glycolysis has 2 phase (1) preparatory phase (2) pay-off phase.
<u>(1) Preparatory phase</u>
During preparatory phase glucose is converted into fructose-1,6-bisphosphate. Till this time the carbon numbering remains the same i.e. if we will label carbon at 6th position of glucose, its position will remian the same in fructose-1,6-bisphosphate that means the labeled carbon will still remain at 6th position.
When fructose-1,6-bisphosphate is further catalyzed with the help of enzyme aldolase it is cleaved into two 3 carbon intermediates which are glyceraldehyde 3-phosphate (GAP) and dihyroxyacetone phosphate (DHAP). In this conversion, the first three carbons of fructose-1,6-bisphosphate become carbons of DHAP while the last three carbons of fructose-1,6-bisphosphate will become carbons of GAP. It simply means that GAP will acquire the last carbon of fructose-1,6-bisphosphate which is labeled. Now the last carbon of GAP which has phosphate will be labeled.
<u>(2) Pay-off phase</u>
During this phase, GAP is dehydrogenated into 1,3-bisphosphoglycerate (BPG) with the help of enzyme glyceraldehyde 3-phosphate dehydrogenase. This oxidation is coupled to phosphorylation of C1 of GAP and this is the reason why 1,3-bisphosphoglycerate has phosphates at 2 positions i.e. at position 1 in which phosphate is newly added and position 3rd which already had labeled carbon.
It is pertinent to mention here that<u> BPG has a mixed anhydride and the bond at C1 is a very high energy bond.</u> In the next step, this high energy bond is hydrolyzed into a carboxylic acid with the help of enzyme phosphoglycerate kinase and the final product is 3-phosphoglycerate. Hence, the carbon with low energy phosphate i.e. the carbon at 3rd position remains labeled.
Answer:
We need 4.28 grams of sodium formate
Explanation:
<u>Step 1:</u> Data given
MW of sodium formate = 68.01 g/mol
Volume of 0.42 mol/L formic acid = 150 mL = 0.150 L
pH = 3.74
Ka = 0.00018
<u>Step 2:</u> Calculate [base)
3.74 = -log(0.00018) + log [base]/[acid]
0 = log [base]/[acid]
0 = log [base] / 0.42
10^0 = 1 = [base]/0.42 M
[base] = 0.42 M
<u>Step 3:</u> Calculate moles of sodium formate:
Moles sodium formate = molarity * volume
Moles of sodium formate = 0.42 M * 0.150 L = 0.063 moles
<u>Step 4:</u> Calculate mass of sodium formate:
Mass sodium formate = moles sodium formate * Molar mass sodium formate
Mass sodium formate = 0.063 mol * 68.01 g/mol
Mass sodium formate = 4.28 grams
We need 4.28 grams of sodium formate
Answer:
See the explanation
Explanation:
In this case, we have to keep in mind that in the monosubstituted product we only have to replace 1 hydrogen with another group. In this case, we are going to use the methyl group 
.
In the axial position, we have a more steric hindrance because we have two hydrogens near to the group. If we have <u>more steric hindrance</u> the molecule would be <u>more unstable</u>. In the equatorial positions, we don't <u>any interactions</u> because the group is pointing out. If we don't have <u>any steric hindrance</u> the molecule will be <u>more stable</u>, that's why the molecule will <u>the equatorial position.</u>
See figure 1
I hope it helps!
I think is D A have a nice day
Good luck bye
Answer:
4.858 g
Explanation:
Start with the formula
density = 
density = 1.98 g/mL
volume = 2.45 mL
mass = ??
rearrange the formula to solve for mass
(density) x (volume) = mass
Add in the substitutes and solve for mass
1.98 g/mL x 2.45 mL = 4.858 g
