A solution containing HCI would likely have
2 answers:
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Answer:
144g of H₂O
Explanation:
3NH₄ClO₄(s) + 3Al → Al₂O₃(s) + AlCl₃(s) + 3NO(g) + 6H₂O(g)
From the equation:
3 moles of NH₄ClO₄ produced 6 moles of H₂O
4 moles of NH₄ClO₄ produced ? moles of H₂O
(4 ₓ 6)/3 = = 8 moles of H₂O
1 mole of H₂O = (1 × 2) + 16 = 18g (The Relative Molecular mass of H₂O)
8 moles of H₂O = ?
Therefore 8 × 18 = 144g
=144g of H₂O
Answer:
Four possible isomers (1–4) for the natural product essramycin. The structure of compound 1 was attributed to essramycin by 1H NMR, 13C NMR, HMBC, HRMS, and IR experiments.
Explanation:
Three synthetic routes were used to prepare all four compounds (Figure 2A). All three reactions utilize 2-(5-amino-4H-1,2,4-triazol-3-yl)-1-phenylethanone (5) as the precursor, whereas each uses different esters (6–8) to construct the pyrimidinone ring. Isomer 1 was prepared by reaction A, which used triazole 5 and ethyl acetoacetate (6) in acetic acid. This was the reaction used in syntheses of essramycin by the Cooper and Moody laboratories.3,4 Reaction B produced compound 2 (minor product) and compound 3 (major product), which were separated chromatographically. This reaction allowed reagent 5 to react with ethyl 3-ethoxy-2-butenoate (7) in the presence of sodium in methanol, under reflux for 24 h. Compound 4 was prepared by reaction C, which was obtained by reflux of 5 and methyl 2-butynoate (8) in n-butanol.
