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Answer:
k = 4.21 * 10⁻³(L/(mol.s))
Explanation:
We know that
k = Ae ------------------- euqation (1)
K= rate constant;
A = frequency factor = 4.36 10^11 M⁻¹s⁻¹;
E = activation energy = 93.1kJ/mol;
R= ideal gas constant = 8.314 J/mol.K;
T= temperature = 332 K;
Put values in equation 1.
k = 4.36*10¹¹(M⁻¹s⁻¹)e
k = 4.2154 * 10⁻³(M⁻¹s⁻¹)
here M =mol/L
k = 4.21 * 10⁻³((mol/L)⁻¹s⁻¹)
or
k = 4.21 * 10⁻³((L/mol)s⁻¹)
or
k = 4.21 * 10⁻³(L/(mol.s))
Answer:
W= 8120 KJ
Explanation:
Given that
Process is isothermal ,it means that temperature of the gas will remain constant.
T₁=T₂ = 400 K
The change in the entropy given ΔS = 20.3 KJ/K
Lets take heat transfer is Q ,then entropy change can be written as
Now by putting the values
Q= 20.3 x 400 KJ
Q= 8120 KJ
The heat transfer ,Q= 8120 KJ
From first law of thermodynamics
Q = ΔU + W
ΔU =Change in the internal energy ,W=Work
Q=Heat transfer
For ideal gas ΔU = m Cv ΔT]
At constant temperature process ,ΔT= 0
That is why ΔU = 0
Q = ΔU + W
Q = 0+ W
Q=W= 8120 KJ
Work ,W= 8120 KJ