Because the concentration of molecules in the gas phase increases with increasing pressure, the concentration of dissolved gas molecules in the solution at equilibrium is also higher at higher pressures
Answer:
Let the mixture is X% by mass of CuSO
4
.5H
2
O and 100 - X % by mass of MgSO
4
.7H
2
O. 5.0 g of mixture will contain 0.05X g CuSO
4
.5H
2
O and 5.0 - 0.05X g MgSO
4
.7H
2
O
The molar masses of CuSO
4
.5H
2
O and MgSO
4
.7H
2
O are 249.7 g/mol and 246.5 g/mol respectively.
The number of moles of CuSO
4
.5H
2
O=
249.7
0.05X
=2.00×10
−4
X moles.
Explanation:
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ΔHrxn = ΣδΗ(bond breaking) - ΣδΗ(bond making)
Bond enthalpies,
N ≡ N ⇒ 945 kJ mol⁻¹
N - Cl ⇒ 192 kJ mol⁻¹
Cl - Cl⇒ 242 kJ mol⁻¹
According to the balanced equation,
ΣδΗ(bond breaking) = N ≡ N x 1 + Cl - Cl x 3
= 945 + 3(242)
= 1671 kJ mol⁻¹
ΣδΗ(bond making) = N - Cl x 3 x 2
= 192 x 6
= 1152 kJ mol⁻¹
δHrxn = ΣδΗ(bond breaking) - ΣδΗ(bond making)
= 1671 kJ mol⁻¹ - 1152 kJ mol⁻¹
= 519 kJ mol⁻¹