Answer:
kf = 1.16 x 10¹⁸
Explanation:
Step 1: [Ni(H₂O)₆]²⁺ + 1en → [Ni(H₂O)₄(en)]²⁺ ΔG°1 = -42.9 kJmol⁻¹
Step 2: [Ni(H₂O)₄(en)]²⁺ + 1en → [Ni(H₂O)₂(en)₂]²⁺ ΔG°2 = -35.8 kJmol⁻¹
Step 3: [Ni(H₂O)₂(en)₂]²⁺ + 1en → [Ni(en)₃]²⁺ ΔG°3 = -24.3 kJmol⁻¹
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Overall reaction: [Ni(H₂O)₆]²⁺ + 3en → [Ni(en)₃]²⁺ ΔG°r
ΔG°r = ΔG°1 + ΔG°2 + ΔG°3
ΔG°r = -42.9 - 35.8 - 24.3
ΔG°r = -103.0 kJmol⁻¹
ΔG°r = -RTlnKf
-103,000 Jmol⁻¹ = - 8.31 J.K⁻¹mol⁻¹ x 298 K x lnKf
kf = e ^(-103,000/-8.31x298)
kf = e ^41.59
kf = 1.16 x 10¹⁸
Answer:
combustion is fast and destructive it also involves a lot of movement of the atoms where erosion is a slow process that does not involve a lot of energy
1. In the remains of organisms such as plants and algae.
2. Air, peace of mind know knowleged and water
3. The Carboniferous
4. Is a colorless , odorless gass that is very flammable.
Answer is: increase the concentration of NiCO₄ and <span>withdraw CO from the products as it is forming.
Balanced chemical reaction: NiCO</span>₄(g) ⇄ Ni(s) + 4CO(g).
According to Le Chatelier's Principle the position of equilibrium
moves to counteract the change:
1) the position of equilibrium will move to the right, so
that the concentration of nickel carbonyl gas decreases again and produce more nickel.
2) the position of equilibrium will move to the right, if we decrease concentration of carbon monoxide, more nickel carbonyl gas will decompose and produce more nickel.
