Answer : BaS
will be the precipitate which will be formed.
Explanation : When all the three solutions namely; 
are mixed together a white precipitate of BaS
is formed as a product in the solution along with the soluble by product of Ammonium nitrate which is 
By use of ideal gas equation PV= nRT where n is the number of moles,P = pressure, V = volume, R= gas constant (0.08206 L. atm/ mol.k) ant T is the temperature,
to calculate the number of moles(n) =PV/RT
convert ml to L, that is 200/1000= 0.2 L
convert mmHg to atm, that is 780mm hg x 1atm/ 760 mm hg= 1.026 atm
convert temperature to kelvin, that is 135 +273= 408 k
n is therefore= (0.2 x 1.026)/ ( 0.08206 x 408)= 6.129 x10^-3 moles
from avogadro constant 1moles = 6.02 x10^23 molecules what about 6 .129 x10^-3 moles
= ( 6.02 x10^23) x (6.129 x10^-3)/ 1mole = 3.69 x10^21 molecules
