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FromTheMoon [43]
2 years ago
15

Which metal does not form cations of differing charges?

Chemistry
1 answer:
valkas [14]2 years ago
8 0

Transition metals

Most transition metals differ from the metals of Groups 1, 2, and 13 in that they are capable of forming more than one cation with different ionic charges. As an example, iron commonly forms two different ions

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The iodide ion reacts with hypochlorite ion (the active ingredient in chlorine bleaches) in the following way:
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Explanation:

(a)  As the given chemical reaction equation is as follows.

           OCl^{-} + I^{-} \rightarrow OI^{-1} + Cl^{-1}

So, when we double the amount of hypochlorite or iodine then the rate of the reaction will also get double. And, this reaction is "first order" with respect to hypochlorite and iodine.

Hence, equation for rate law of reaction will be as follows.

              Rate = K \times [OCl^{-}] \times [l^{-}]

(b)  Since, the rate equation is as follows.

                    Rate = K [OCl^{-}][l^{-}]

Let us assume that ([OCl^{-}] = [l^{-}])

Putting the given values into the above equation as follows.

             1.36 \times 10^{-4} = K \times (1.5 \times 10^{-3})^2

            1.36 \times 10^{-4} = K \times (2.25 \times 10^{-6})

                   K = \frac{1.36 \times 10^{-4}}{2.25 \times 10^{-6}}

                      = 60.4 M^{-1}sec^{-1}

Hence, the value of rate constant for the given reaction is 60.4 M^{-1}sec^{-1} .

(c) Now, we will calculate the rate as follows.

                Rate = K [OCl^{-}][l^{-}]

                         = 60.4 \times (1.8 \times 10^{3}) \times (6.0 \times 10^{4})

                        = 6.52 \times 10^{5}

Therefore, rate when [OCl^{-}] = 1.8 \times 10^{3} M and [I^{-}]= 6.0 \times 10^{4} M is  6.52 \times 10^{5}.

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