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amm1812
3 years ago
5

Calculate the volume of "dry" hydrogen that would be produced by one mole of magnesium at

Chemistry
1 answer:
kakasveta [241]3 years ago
5 0

Answer:The volume of H2 = 243mL = 0.243 L

Pressure of H2 gas collected = 745 mm

Pressure of H2 dry gas = P of H2 collected - vapor pressure of water = 745- 23.78 = 721.22 mm

= 721.22mm /760mm/atm

Temperature = 25C = 25+273= 298 K

Using the ideal gas equation

PV = nRT

or PV = (mass/molar mass) RT

(721.22/760)atm x 0.243L = (mass/ 2g/mol) x 0.0821L.atm/mol.K x 298K

Thus mass of H2 formed = 0.0188 g

Explanation:

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Answer: 2 moles of H_2O will be formed.

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Explanation:

The reaction equation will be as follows.

           CO_{2}(aq) + H_{2}O \rightleftharpoons H^{+}(aq) + HCO^{-}_{3}(aq)

Calculate the amount of CO_{2} dissolved as follows.

             CO_{2}(aq) = K_{CO_{2}} \times P_{CO_{2}}

It is given that K_{CO_{2}} = 0.032 M/atm and P_{CO_{2}} = 1.9 \times 10^{-4} atm.

Hence, [CO_{2}] will be calculated as follows.

           [CO_{2}] = K_{CO_{2}} \times P_{CO_{2}}          

                           = 0.032 M/atm \times 1.9 \times 10^{-4}atm

                           = 0.0608 \times 10^{-4}

or,                        = 0.608 \times 10^{-5}

It is given that K_{a} = 4.46 \times 10^{-7}

As,      K_{a} = \frac{[H^{+}]^{2}}{[CO_{2}]}

          4.46 \times 10^{-7} = \frac{[H^{+}]^{2}}{0.608 \times 10^{-5}}  

               [H^{+}]^{2} = 2.71 \times 10^{-12}

                      [H^{+}] = 1.64 \times 10^{-6}

Since, we know that pH = -log [H^{+}]

So,                      pH = -log (1.64 \times 10^{-6})

                                 = 5.7

Therefore, we can conclude that pH of water in equilibrium with the atmosphere is 5.7.

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3 years ago
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