<span>the water is the solvent, and the powder is the solute. This is also a solution altogether. </span>
<span>We need to calculate the equivalent amount in units of moles of ammonium ions from the mass units. For this we need the molar mass of the substances involved. We calculate as follows:
31.3 g </span>(NH4)2CO3 ( 1 mol (NH4)2CO3 / 96.09 g (NH4)2CO3) ( 2 mol NH4 / 1 mol (NH4)2CO3 ) = 0.65 mol <span>ammonium ions</span>
Ca, they only have two valence electrons, in order to become more stable, they would like to lose all of them
pH of the buffer solution is 1.76.
Chemical dissociation of formic acid in the water:
HCOOH(aq) ⇄ HCOO⁻(aq) + H⁺(aq)
The solution of formic acid and formate ions is a buffer.
[HCOO⁻] = 0.015 M; equilibrium concentration of formate ions
[HCOOH] + [HCOO⁻] = 1.45 M; sum of concentration of formic acid and formate
[HCOOH] = 1.45 M - 0.015 M
[HCOOH] = 1.435 M; equilibrium concentration of formic acid
pKa = -logKa
pKa = -log 1.8×10⁻⁴ M
pKa = 3.74
Henderson–Hasselbalch equation: pH = pKa + log(cs/ck)
pH = 3.74 + log (0.015 M/1.435 M)
pH = 3.74 - 1.98
pH = 1.76
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Answer:
a. 2 HgO(s) ⇒ 2 Hg(l) + O₂(g)
b. 0.957 g
Explanation:
Step 1: Write the balanced equation
2 HgO(s) ⇒ 2 Hg(l) + O₂(g)
Step 2: Convert 130.0 °C to Kelvin
We will use the following expression.
K = °C + 273.15
K = 130.0°C + 273.15
K = 403.2 K
Step 3: Calculate the moles of O₂
We will use the ideal gas equation.
P × V = n × R × T
n = P × V/R × T
n = 1 atm × 0.0730 L/0.0821 atm.L/mol.K × 403.2 K
n = 2.21 × 10⁻³ mol
Step 4: Calculate the moles of HgO that produced 2.21 × 10⁻³ moles of O₂
The molar ratio of HgO to O₂ is 2:1. The moles of HgO required are 2/1 × 2.21 × 10⁻³ mol = 4.42 × 10⁻³ mol.
Step 5: Calculate the mass corresponding to 4.42 × 10⁻³ moles of HgO
The molar mass of HgO is 216.59 g/mol.
4.42 × 10⁻³ mol × 216.59 g/mol = 0.957 g
