Answer:
The empirical formula is CH2O, and the molecular formula is some multiple of this
Explanation:
In 100 g of the unknown, there are 40.0⋅g12.011⋅g⋅mol−1 C; 6.7⋅g1.00794⋅g⋅mol−1 H; and 53.5⋅g16.00⋅g⋅mol−1 O.
We divide thru to get, C:H:O = 3.33:6.65:3.34. When we divide each elemental ratio by the LOWEST number, we get an empirical formula of CH2O, i.e. near enough to WHOLE numbers. Now the molecular formula is always a multiple of the empirical formula; i.e. (EF)n=MF.So 60.0⋅g⋅mol−1=n×(12.011+2×1.00794+16.00)g⋅mol−1.Clearly n=2, and the molecular formula is 2×(CH2O) = CxHyOz.
The rate law depicts the effect of concentration on reaction rate. Second mechanism 2NO(g) ⇄ N₂O₂(g) [fast], N₂O₂(g) + O₂(g) → 2NO₂(g) [slow] is most reasonable. Thus, option b is correct.
<h3>What is rate law?</h3>
Rate law and equation give the rate at which the reaction takes place under the influence of the concentration of the reactants. The balanced chemical reaction is given as,
2NO(g) + O₂(g) → 2NO₂(g)
The rate of the equation is given as,
rate = k [NO]² [O₂]
In a multi-step chemical reaction, the slowest step is the rate-determining step. The second mechanism is given as,
2NO (g) → N₂O₂ (g) [fast]
N₂O₂(g) +O₂(g) → 2NO₂ (g) [slow]
Rate is given as,
rate = k [N₂O₂] [O₂]
Therefore, option b. the second mechanism is the most reasonable.
Learn more about rate law, here:
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The order of components in a typical flame atomic absorption spectrometer is hollow cathode lamp--flame--monochromator--detector
<u>Explanation:</u>
- The hollow cathode lamp practices a cathode created of the element of interest with a low internal pressure of inert gas.
- Remove scattered light of other wavelengths from the flame. AAS flame includes aiming at first the fuel than the oxidant and then lighting the flame with the instrument's auto-ignition system. Applying flame Ddtroy any analyte ions and breakdown complexes.
- The process of the monochromator is to divide analytical lines photons moving through the flame
- Photomultiplier tube (PMT) as the detector the PMT determines the intensity of photons of the analytical line exiting the monochromator.