When ketone is reacted with phosphorous pentachloride, chlorination takes place at the carbonyl carbon with substitution of the oxygen atom to give a geminal dichloride (with 2 Cl atoms on same carbon) according to the following equation:
so we can say that acetone is converted into 2,2-dichloropropane by action of PCl₅
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Yes, they are the same. They are equivalent.
Answer:
V₂ = 15.3
Explanation:
Given data:
Initial volume = 12.0 L
Initial temperature = 20°C
Final temperature =100°C
Final volume = ?
Solution:
First of all we will convert the temperature into kelvin.
20°C + 273 = 293 K
100°C + 273 = 373 K
Formula:
V₁/T₁ = V₂/T₂
V₁ = Initial volume
T₁ = Initial temperature
V₂ = Final volume
T₂ = Final temperature
Now we will put the values in formula.
V₁/T₁ = V₂/T₂
V₂ = V₁T₂/T₁
V₂ = 12.0 L × 373 K / 293 k
V₂ = 4476 L.K /293 k
V₂ = 15.3
V₂ = 1566 L.K / 298 K
V₂ = 5.3 L
