Answer:
The unknown solution had the higher concentration.
Explanation:
When two solutions are separated by a semi-permeable membrane, depending on the concentration gradient between the two solutions, there is a tendency for water molecules to move across the semi-permeable in order to establish an equilibrium concentration between the two solutions. This movement of water molecules across a semi-permeable membrane in response to a concentration gradient is known as osmosis. In osmosis, water molecules moves from a region of lower solute concentration or higher water molecules concentration to a region of higher solute concentration or lower water molecules concentration until equilibrium concentration is attained.
Based on the observation that when the glucose solution described in part A is connected to an unknown solution via a semipermeable membrane, the unknown solution level rises, it means that water molecules have passed from the glucose solution through the semipermeable membrane into the unknown solution. Therefore, the solution has a higher solute concentration than the glucose solution.
Answer:
a=28600J; b=90.6 J/K; c=402 torr
Explanation:
(a) considering the data given
Vapour pressure P1 =0 at Temperature T1 = 42.43˚C,
Vapour pressure P2 = 273.15 at Temperature T2= 315.58 K)
Using the Clausius-Clapeyron Equation
ln (P2/P1) = (ΔH/R)(1/T2 - 1/T1)
In 760/140 = ΔH/8.314 J/mol/K × (1/315.58K -- 1/273.15K)
ΔH vap= +28.6 kJ/mol or 28600J
(b) using the Equation ΔG°=ΔH° - TΔS to solve forΔS.
Since ΔG at boiling point is zero,
ΔS =(ΔH°vap/Τb)
ΔS = 28600 J/315.58 K
= 90.6 J/K
(c) using ln (P2/P1) = (ΔH/R)(1/T2 - 1/T1)
ln P298 K/1 atm = 28600 J/8.314 J/mol/K × (1/298.15K - 1/315.58K)
P298 K = 0.529 atm
= 402 torr
The correct answer is B 25
