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Aneli [31]
3 years ago
6

Write the balanced chemical equation between H2SO4 and KOH in aqueous solution. This is called a neutralization reaction and wil

l produce whater and potassium sulfate. Phases are optional.
0.650 L of 0.430 M H2SO4 is mixed with 0.600 L of 0.240 M KOH. What concentration of sulfuric acid remains after neutralization?
Chemistry
1 answer:
emmainna [20.7K]3 years ago
7 0

Answer:

0.166M

Explanation:

In a neutralization, the acid, H₂SO₄, reacts with a base, KOH, to produce a salt, K₂SO₄ and water. The reaction is:

H₂SO₄ + 2KOH → K₂SO₄ + 2H₂O

To solve this problem, we need to determine moles of H2SO4 and moles of KOH that reacts to find the moles of sulfuric acid that remains after the reaction:

<em>Moles H2SO4:</em>

0.650L * (0.430mol /L) = 0.2795moles H2SO4

<em>Moles KOH:</em>

0.600L * (0.240mol / L) = 0.144 moles KOH

Moles of sulfuric acid that reacts with 0.144 moles of KOH are:

0.144 moles KOH * (1mol H2SO4 / 2 mol KOH) = 0.072 moles of H2SO4 react.

And remain:

0.2795moles H2SO4 - 0.072moles H2SO4 = 0.2075 moles of H2SO4 reamains.

In 0.650L + 0.600L = 1.25L:

Molar concentration of sulfuric acid:

0.2075 moles of H2SO4 / 1.25L =

<h3>0.166M</h3>
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Answer : The formal charge on the central nitrogen atom is, (+1)

Explanation :

Resonance structure : Resonance structure is an alternating method or way of drawing a Lewis-dot structure for a compound.

Resonance structure is defined as any of two or more possible structures of the compound. These structures have the identical geometry but have different arrangements of the paired electrons. Thus, we can say that the resonating structure are just the way of representing the same molecule.

First we have to determine the Lewis-dot structure of CNO^-.

Lewis-dot structure : It shows the bonding between the atoms of a molecule and it also shows the unpaired electrons present in the molecule.

In the Lewis-dot structure the valance electrons are shown by 'dot'.

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As we know that carbon has '4' valence electrons, nitrogen has '5' valence electrons and oxygen has '6' valence electrons.

Therefore, the total number of valence electrons in CNO^- = 4 + 5 + 6 + 1= 16

According to Lewis-dot structure, there are 8 number of bonding electrons and 8 number of non-bonding electrons.

Now we have to determine the formal charge for each atom.

Formula for formal charge :

\text{Formal charge}=\text{Valence electrons}-\text{Non-bonding electrons}-\frac{\text{Bonding electrons}}{2}

For structure 1 :

\text{Formal charge on O}=6-6-\frac{2}{2}=-1

\text{Formal charge on C}=4-2-\frac{6}{2}=-1

\text{Formal charge on N}=5-0-\frac{8}{2}=+1

For structure 2 :

\text{Formal charge on O}=6-4-\frac{4}{2}=0

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\text{Formal charge on N}=5-0-\frac{8}{2}=+1

For structure 3 :

\text{Formal charge on O}=6-2-\frac{6}{2}=+1

\text{Formal charge on C}=4-6-\frac{2}{2}=-3

\text{Formal charge on N}=5-0-\frac{8}{2}=+1

The best Lewis-dot structure is, structure 1.

Thus, the formal charge on the central nitrogen atom is, (+1)

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