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vagabundo [1.1K]
3 years ago
5

A student is trying to determine the rate law of a chemical reaction. When the initial concentration is varied, the initial reac

tion rate is always the same. The student concludes that something must be wrong with the chemicals or reaction and decides to increase the temperature. What can you say about this conclusion
Chemistry
1 answer:
boyakko [2]3 years ago
8 0

Answer:

His conclusion is wrong

Explanation:

Now we must know that there are various rate laws.

In a zero order rate law, the rate of reaction is independent of the initial concentration of reactants. Hence varying the initial concentration of the reactants results in no change of the rate of reaction.

In first and second order rate laws, the rate of reaction varies with the concentration of one or two reactants in either case respectively.

Having said these, the student does not need to change the temperature but rather designate the reaction as zero order. The rate of reaction is independent of the initial concentration of reactants.

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Answer:

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5 0
3 years ago
A stock solution of HNO3 is prepared and found to contain 13.5 M of HNO3. If 25.0 mL of the stock solution is diluted to a final
salantis [7]

Answer : The correct option is, (C) 0.675 M

Explanation :

Using neutralization law,

M_1V_1=M_2V_2

where,

M_1 = concentration of HNO_3 = 13.5 M

M_2 = concentration of diluted solution = ?

V_1 = volume of HNO_3 = 25.0 ml  = 0.0250 L

conversion used : (1 L = 1000 mL)

V_2 = volume of diluted solution = 0.500 L

Now put all the given values in the above law, we get the concentration of the diluted solution.

13.5M\times 0.0250L=M_2\times 0.500L

M_2=0.675M

Therefore, the concentration of the diluted solution is 0.675 M

8 0
3 years ago
When 0.250 moles of KCl are added to 200.0 g of water in a constant pressure calorimeter a temperature change is observed. Given
777dan777 [17]

Explanation:

Upon dissolution of KCl heat is generated and temperature of the solution raises.

Therefore, heat generated by dissolving 0.25 moles of KCl will be as follows.

             17.24 kJ/mol \times 0.25 mol

                = 4.31 kJ

or,             = 4310 J      (as 1 kJ = 1000 J)

Mass of solution will be the sum of mass of water and mass of KCl.

       Mass of Solution = mass of water + (no. of moles of KCl × molar mass)

                                    = 200 g + (0.25 mol \times 54.5 g/mol)

                                    = 200 g + 13.625 g

                                    = 213.625 g

Relation between heat, mass and change in temperature is as follows.

                             Q = mC \Delta T

where,    C = specific heat of water = 4.184 J/g^{o}C

Therefore, putting the given values into the above formula as follows.

                     Q = mC \Delta T

            4310 J = 213.625 g \times 4.184 J/g^{o}C \times \Delta T      

              \Delta T = 4.82^{o}C

Thus, we can conclude that rise in temperature will be 4.82^{o}C.

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3 years ago
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Answer:

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Explanation:

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