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Sonja [21]
3 years ago
11

In a certain electrolysis experiment, 1.24 g of Ag were deposited in one cell (containing an aqueous AgNO3 solution), while 0.65

0 g of an unknown metal X was deposited in another cell (containing an aqueous XCl3 solution) in series with the AgNO3 cell. Calculate the molar mass of X.
Chemistry
1 answer:
eduard3 years ago
7 0

Answer:

The correct answer is 169.56 g/mol.

Explanation:

Based on the given information, the mass of Ag deposited is 1.24 g, and the mass of unknown metal X deposited in another cell is 0.650 g. The number of moles of electrons can be determined as,

= 1.24 g Ag * 1mol Ag/107.87 g/mol Ag * 1 mol electron/1 mol Ag ( the molecular mass of Ag is 107.87 g/mol)

= 0.0115 mole of electron

The half cell reaction for the metal X is,  

X^3+ (aq) + 3e- = X (s)

From the reaction, it came out that 3 faraday will reduce one mole of X^3+.  

The molar mass of X will be,  

= 0.650 g/0.0115 *3 mol electron/1 mol

= 56.52 * 3

= 169.56 g/mol

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3 years ago
1. For each of the molecules below, determine the electron geometry, molecule geometry, and bond
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Answer:

CCl4- tetrahedral bond angle 109°

PF3 - trigonal pyramidal bond angles less than 109°

OF2- Bent with bond angle much less than 109°

I3 - linear with bond angles = 180°

A molecule with two double bonds and no lone pairs - linear molecule with bond angle =180°

Explanation:

Valence shell electron-pair repulsion theory (VSEPR theory) helps us to predict the molecular shape, including bond angles around a central atom, of a molecule by examination of the number of bonds and lone electron pairs in its Lewis structure. The VSEPR model assumes that electron pairs in the valence shell of a central atom will adopt an arrangement which tends to minimize repulsions between these electron pairs by maximizing the distance between them. The electrons in the valence shell of a central atom are either bonding pairs of electrons, located primarily between bonded atoms, or lone pairs. The electrostatic repulsion of these electrons is reduced when the various regions of high electron density assume positions as far apart from each other as possible.

Lone pairs and multiple bonds are known to cause more repulsion than single bonds and bond pairs. Hence the presence of lone pairs or multiple bonds tend to distort the molecular geometry geometry away from that predicted on the basis of VSEPR theory. For instance CCl4 is tetrahedral with no lone pair and four regions of electron density around the central atom. This is the expected geometry. However OF2 also has four regions of electron density but has a bent structure. The molecule has four regions of electron density but two of them are lone pairs causing more repulsion. Hence the observed bond angle is less than 109°.

8 0
3 years ago
A student is given a 2.002 g sample of unknown acid and is told that it might be butanoic acid, a monoprotic acid (HC4H7O2, equa
Elina [12.6K]

<u>Answer:</u> The identity of the unknown acid is butanoic acid or ascorbic acid.

<u>Explanation:</u>

To calculate the number of moles for given molarity, we use the equation:

\text{Molarity of the solution}=\frac{\text{Moles of solute}\times 1000}{\text{Volume of solution (in L)}}

Molarity of NaOH solution = 0.570 M

Volume of solution = 39.55 mL

Putting values in above equation, we get:

0.570M=\frac{\text{Moles of NaOH}\times 1000}{39.55}\\\\\text{Moles of NaOH}=\frac{0.570\times 39.55}{1000}=0.0225mol

The chemical equation for the reaction of NaOH and monoprotic acid follows:

NaOH+HX\rightarrow NaX+H_2O

By Stoichiometry of the reaction:

1 mole of NaOH reacts with 1 mole of HX

So, moles of monoprotic acid = 0.0225 moles

The chemical equation for the reaction of NaOH and diprotic acid follows:

2NaOH+H_2X\rightarrow 2NaX+2H_2O

By Stoichiometry of the reaction:

2 moles of NaOH reacts with 1 mole of diprotic acid

So, moles of diprotic acid = \frac{0.0225}{2}=0.01125moles

To calculate the number of moles, we use the equation:

\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}

  • <u>For butanoic acid:</u>

Mass of butanoic acid = 2.002 g

Molar mass of butanoic acid = 88 g/mol

Putting values in above equation, we get:

\text{Moles of butanoic acid}=\frac{2.002g}{88g/mol}=0.02275mol

  • <u>For L-tartaric acid:</u>

Mass of L-tartaric acid = 2.002 g

Molar mass of L-tartaric acid = 150 g/mol

Putting values in above equation, we get:

\text{Moles of L-tartaric acid}=\frac{2.002g}{150g/mol}=0.0133mol

  • <u>For ascorbic acid:</u>

Mass of ascorbic acid = 2.002 g

Molar mass of ascorbic acid = 176 g/mol

Putting values in above equation, we get:

\text{Moles of ascorbic acid}=\frac{2.002g}{176g/mol}=0.01137mol

As, the number of moles of butanoic acid and ascorbic acid is equal to the number of moles of acid getting neutralized.

Hence, the identity of the unknown acid is butanoic acid or ascorbic acid.

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