It would be C
2 kg x 1000 g/kg x 1mol/18.02 x 6.03 kj/mol = 669kj
The correct answer is a. This is because the pH of a solution is defined as -log10(concentration of H+ ions). An inverse logarithmic scale such as this means that a solution with a lower concentration of H+ ions will have a higher pH than one with a higher concentration. Therefore we know that the pH of the second sample will be higher than the first.
Since the logarithmic scale has the base 10, a change by 1 on the scale is a consequence of multiplication/division of the H+ concentration by a factor of 10. As the scale is inverse, this means that a decrease of concentration by factor 1000 is equivalent to increasing the pH by (1000/10) = 3.
To cut this short and for your understanding, ionic bond is formed between metals (mostly right column in periodic table). Covalent bond is formed between non-metals (mostly left column in periodic table). So polar covalent is also a covalent bond but it is polar, which means the shape of molecules are not symmetrical hence maybe an atom in a molecule has most of the electron attracted to it causing itself to be partial negative (since electron are negatively charged) and the other atom has its electron being attracted by others became partial positive. Polar covalent can also be when H atom is binding either to F, O or N (also known as hydrogen bond).