Answer: The most likely partial pressures are 98.7MPa for NO₂ and 101.3MPa for N₂O₄
Explanation: To determine the partial pressures of each gas after the increase of pressure, it can be used the equilibrium constant Kp.
For the reaction 2NO₂ ⇄ N₂O₄, the equilibrium constant is:
Kp = 
where:
P(N₂O₄) and P(NO₂) are the partial pressure of each gas.
Calculating constant:
Kp = 
Kp = 0.0104
After the weights, the total pressure increase to 200 MPa. However, at equilibrium, the constant is the same.
P(N₂O₄) + P(NO₂) = 200
P(N₂O₄) = 200 - P(NO₂)
Kp = 
0.0104 = ![\frac{200 - P(NO_{2}) }{[P(NO_{2} )]^{2}}](https://tex.z-dn.net/?f=%5Cfrac%7B200%20-%20P%28NO_%7B2%7D%29%20%20%7D%7B%5BP%28NO_%7B2%7D%20%29%5D%5E%7B2%7D%7D)
0.0104
+
- 200 = 0
Resolving the second degree equation:
=
= 98.7
Find partial pressure of N₂O₄:
P(N₂O₄) = 200 - P(NO₂)
P(N₂O₄) = 200 - 98.7
P(N₂O₄) = 101.3
The partial pressures are
= 98.7 MPa and P(N₂O₄) = 101.3 MPa
Answer:
The specific heat of iron is 0.45 J/g.°C
Explanation:
The amount of heat absorbed by the metal is given by:
heat = m x Sh x ΔT
From the data, we have:
heat = 180.8 J
mass = m = 22.44 g
ΔT = Final temperature - Initial temperature = 39.0°C - 21.1 °C = 17.9°C
Thus, we calculate the specific heat of iron (Sh) as follows:
Sh = heat/(m x ΔT) = (180.8 J)/(22.44 g x 17.9°C) = 0.45 J/g.°C
Answer:
<h2>0.102 L</h2>
Explanation:
The new pressure can be found by using the formula for Boyle's law which is

Since we are finding the new volume

From the question we have

We have the final answer as
<h3>0.102 L</h3>
Hope this helps you